Allylic/Benzylic Bromination With N-Bromo Succinimide (NBS)

Allylic/Benzylic Bromination With N-Bromo Succinimide (NBS)

Assessment

Interactive Video

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Chemistry, Science

11th Grade - University

Hard

The video explains radical halogenation, focusing on bromination at allylic and benzylic positions. It introduces N-Bromosuccinimide (NBS) as a preferred reagent over molecular bromine to avoid unwanted addition reactions. The mechanism involves bromine radicals interacting with allylic substrates, leading to successful bromination. Key to the process is maintaining low concentrations of species that react with pi bonds, allowing radical chemistry to proceed.

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2 questions

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1.

OPEN ENDED

3 mins • 1 pt

What are the advantages of using NBS over molecular bromine in bromination reactions?

2.

OPEN ENDED

3 mins • 1 pt

How does resonance stabilization play a role in the formation of allylic radicals?