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Kinetics practice 2

Total questions: 10

Worksheet time: 20mins

Name
Class
Date
1.

Which statements are correct?

I. The activation energy of a reaction is not affected by temperature.

II. A catalyst reduces the enthalpy change of a reaction.

III. Catalysts provide alternative reaction pathways.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

2.

Which factors can affect the rate of reaction?

I. Particle size of solid reactant

II. Concentration of reacting solution

III. Pressure of reacting gas

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

3.

The diagram shows the energy profile for a catalysed and uncatalysed reaction.

Which represents the enthalpy change, ΔH, and the activation energy, Ea, for the catalysed reaction?

a)

ΔH is z, Ea (catalysed reaction) is x + z

b)

ΔH is z, Ea (catalysed reaction) is z + y

c)

ΔH is -z, Ea (catalysed reaction) is x

d)

ΔH is z + x, Ea (catalysed reaction) is x

4.

Which variable is best to use when determining the rate of decomposition of hydrogen peroxide?


2H2O2(l) → 2H2O(l)+O2(g)

a)

Volume of solution

b)

Volume of gas

c)

pH of solution

d)

Conductivity of solution

5.

Which is a correct unit for expressing the rate of a reaction?

a)

mol L-1 s-1

b)

mol L-1 s

c)

mol s

d)

mol-1 L s-1

6.

1.00 mol L−1 solution of hydrochloric acid is added to 2.00 g of small pieces of calcium carbonate at 20°C. The volume of carbon dioxide produced against time is plotted to give curve P.


Which change will produce curve Q, given that calcium carbonate is always the limiting reagent?

a)

Increasing the volume of the hydrochloric acid to 200 mL

b)

Increasing the mass of calcium carbonate to 4.00 g

c)

Increasing the concentration of the hydrochloric acid to 2.00 mol L−1

d)

Replacing the 2.00 g of small pieces of calcium carbonate with 2.00 g of larger pieces of calcium carbonate

7.

Which quantity can be changed by the use of a catalyst?

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

8.

The diagram represents the Maxwell‒Boltzmann energy distribution curve of the reactants for a chemical reaction with different activation energies, Ea1 and Ea2.


What is the reason why the rate of the reaction with activation energy Ea2 is greater?

a)

More frequent collisions between the particles occur.

b)

More energetic collisions between the particles occur.

c)

A catalyst has been added.

d)

The temperature is higher.

9.

Which change increases the rate of a chemical reaction?

a)

Increasing the size of solid reactant particles

b)

Decreasing the concentration of aqueous reactants

c)

Increasing the surface area of a solid reactant

d)

Decreasing the pressure of gaseous reactants

10.

Which is not affected by an increase in temperature?

a)

Rate of reaction

b)

Collision frequency

c)

Collision geometry

d)

% of molecules with EEa