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Gen Chem 2 Final Recitation Review

Total questions: 21

Worksheet time: 43mins

Name
Class
Date
1.

What type of reaction is the conversion of an alkene to an alkane?

a)

hydrogenation

b)

dehydrogenation

c)

methasis

d)

acid/base

2.

Draw the skeletal structure for propanal

a)
b)
c)
d)
3.

Name this compound:

a)

4,5-dichloro-3,3-dimethyl heptane

b)

3,4-dichloro-5,5-dimethyl hexane

c)

4,5-chloro-3-methyl heptane

d)

3,4-dichloro-5,5-dimethyl heptane

4.

What is the predominant IMF present in butanol?

a)

London dispersion

b)

Hydrogen bonding

c)

dipole-dipole

d)

no IMFs

5.

Name this ester:

a)

propyl ethyl ester

b)

propyl ethanoate

c)

ethyl propanoate

d)

pentanoic ester

6.

What are the most important intermolecular attractions in a solution of oxygen gas and bromine liquid?

a)

dipole-dipole

b)

London dispersion

c)

hydrogen bonding

d)

ion-dipole

7.

Which of these is an electrolyte?

a)

glucose

b)

methanol

c)

sucrose

d)

sodium chloride

8.

What is the freezing point of a solution of 6.2g MgCl2 in 730 g H2O? Remember ΔT = i Kf m; Kf = 1.86 °C/m

a)

-0.1659 °C

b)

-0.50 °C

c)

-0.3318 °C

d)

-0.0004978 °C

9.

What's the mole fraction if HNO3 in a solution of 68% HNO3 in H2O?

a)

0.622

b)

0.378

c)

2.855

d)

1.079

10.

If ΔH° = 465 kJ/mol and ΔS° = 552 J/mol K, below what temperature will the reaction occur spontaneously? Remember ΔG° = ΔH° - T ΔS°

a)

0.842 K

b)

842.4 K

c)

369 K

d)

0.438 K

11.

What is the rate law for this equation:

a)

rate = k [CO2] [OH-]

b)

rate = k [HCO3-] [CO2] [OH-]

c)

rate = k [HCO3-] / [CO2] [OH-]

d)

rate = k [HCO3-]

12.

Find the activation energy if T1 = 555 K, T2 = 700K, K1 = 6.23 x 10-7 M-1s-1, K2 = 2.01 x 10-3 M-1s-1

a)

-180 J/mol

b)

180 kJ/mol

c)

-180 kJ/mol

d)

180 J/mol

13.

What are the signs of ΔS°, ΔH°, and ΔG° for the sublimation of dry ice at 25°C?

a)

+, +, +

b)

+, +, -

c)

-, -, -

d)

-, -, +

14.

What is the rate constant for the decomposition of ibuprofen in water if the half life is 24 days at 25°C? Assume first order kinetics where t1/2 = (1/k) ln 2

a)

0.0125 days-1

b)

0.24 days-1

c)

0.029 days-1

d)

16.63 days-1

15.

Which of the following are ways to determine if a proposed mechanism is plausible?

a)

the sum of the elementary steps must yield the overall equation

b)

the derived rate law for the proposed mechanism must be consistent with the experimentally determined rate law

c)

there must be intermediates present in each reaction

d)

elementary steps should be uni- or bi- molecular

16.

What is [Cl2] if Kc = 7.1, [BrCl] = 0.014 M, and [Br2] = 0.0023 M?

a)

0.015 M

b)

0.0023 M

c)

0.86 M

d)

0.012 M

17.

What is the pH of a solution of [OH-] = 3.16 x 10-10 M?

a)

9.5

b)

4.5

c)

1.15

d)

12.85

18.

Which direction would the reaction shift if (a) Chlorine gas was added, (b), pressure was increased, and (c) HCl was removed?

a)

(a) left (b) right (c) lelft

b)

(a) right (b) right (c) left

c)

(a) left (b) right (c) stay the same

d)

(a) stay the same (b) left (c) left

19.

What could be done to increase nitrogen gas concentration?

a)

add H2O

b)

remove H2O

c)

increase pressure

d)

add H2

20.

Calculate the concentration of PCl5 of 0.03 mol PCl5 is added to 3L water at 300K (use an ice box!)

a)

0.0074 M

b)

0.0026 M

c)

0.0174 M

d)

0.0385 M

21.

Label the acid, base, conjugate acid, and conjugate base (answers L to R)

a)

base, acid, conjugate base, conjugate acid

b)

acid, base, conjugate acid, conjugate base

c)

acid, base, conjugate base, conjugate acid

d)

base, acid, conjugate acid, conjugate base