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PhyChem1Ex7

Total questions: 8

Worksheet time: 4mins

Name
Class
Date
1.

The Rf is

a)

the retention factor

b)

a derived number between 0.0 and 1.0

c)

a measurement of the chromatographic behavior of a substance

d)

all of the above

2.

A substance with a low affinity for the stationary phase will have a relatively

a)

low Rf

b)

high Rf

c)

cannot be determined

3.

A substance with a high affinity for the mobile phase will tend to be

a)

high Rf

b)

low Rf

c)

similar in polarity to the stationary phase

4.

Which functional group was formed as the condensation product of the air pollutants and 2,4-DNPH?

a)

hydramine

b)

hydroxone

c)

hydrazine

d)

hydrazone

5.

A substance which traveled half as far from the origin as the solvent front on a TLC plate has an Rf of what?

a)

1.0

b)

0.5

c)

0.0

d)

cannot be determined

6.

In a chromatographic separation, substances should have

a)

similar distributions between the mobile and stationary phases

b)

high affinity for both phases

c)

low affinity for both phases

d)

dissimilar distributions between both phases

7.

The denominator in the Rf calculation is the

a)

distance solvent level moved from origin to end point

b)

solvent front

c)

eluent front

d)

all of the above

8.

If you ran a TLC plate in 20% ethyl acetate in hexanes and measured an Rf of 0.1 for your substance, how would you change the mobile phase to increase the Rf?

a)

Add more of the 20% solvent

b)

Add more ethyl acetate

c)

Add more hexanes

d)

Add more substance