wayground logo

Free Printable Worksheets

Font size

S
M
L
XL
Worksheets

Thermochemistry form 5

Total questions: 16

Worksheet time: 40mins

Name
Class
Date
1.

Which statement is correct about exothermic reaction?

a)

The heat absorbed during bond breaking is more than the heat released during bond formation

b)

The heat absorbed during bond breaking is less than the heat released during bond formation

c)

The heat absorbed during bond breaking is equal to the heat released during bond formation

d)

No heat is absorbed or released during bond breaking and bond formation

2.

The diagram shows the energy profile for the formation of T from R and S.


What is the activation energy for the reaction?

a)

y kJ mol-1

b)

(x + y) kJ mol-1

c)

x kJ mol-1

d)

(x-y) kJ mol-1

3.

The reaction between nitrogen and oxygen can be represented by the following equation:

Which of the following energy level diagrams represent the above reaction?

a)
b)
c)
d)
4.

An experiment was carried out to determine the heat of precipitation for the reaction between silver nitrate and sodium chloride. Table 5 shows the temperature reading of both solutions.


Based on Table 5, which of the following is true?

[Specific heat capacity: 4.0 J g-1 °C-1; Relative atomic mass: Ag=108; Cl=35.5]


CHOOSE MORE THAN 1 ANSWER!

a)

7.2 g white precipitate is formed.

b)

Heat released during the experiment is 2100 J

c)

The amount of silver nitrate used is 0.05 mol

d)

Heat released during the formation of bonds is more than heat absorbed during the breaking of bonds.

5.

In an experiment 2.4 g of magnesium powder is added to 100 cm3 of 2.0 mol dm-3 copper(II) sulphate solution. The temperature of the mixture increases by 1.0 °C. What is the heat of reaction in the experiment?

[Specific heat capacity of a solution = 4.2 J g-1 0C-1; Relative atomic mass of Mg=24]

a)

- 0.42 kJ mol-1

b)

- 0.48 kJ mol-1

c)

- 4.20 kJ mol-1

d)

- 4.80 kJ mol-1

6.

Which of the following acids, when added to 50 cm3 of 0.01 mol dm-3 sodium hydroxide solution, produce the same rise in temperature of the mixture?

a)

50 cm3 of 0.01 mol dm-3 hydrochloric acid

b)

25 cm3 of 0.01 mol dm-3 sulphuric acid

c)

50 cm3 of 0.01 mol dm-3 nitric acid

d)

50 cm3 of 0.01 mol dm-3 ethanoic acid

7.

When 50 cm3 of 1.0 moldm-3 nitric acid is mixed with 50 cm3 of 1.0 moldm-3 sodium hydroxide solution the temperature increases by 6.0 °C. What is the temperature change if the experiment is repeated using 50 cm3 of 2.0 mol dm-3 nitric acid with 50 cm3 of 1.0 mol dm-3 sodium hydroxide?

a)

3.0 °C

b)

6.0 °C

c)

9.0 °C

d)

12.0 °C

8.

Below are two thermo chemical equations for the neutralization process.


NaOH + HCl -- > NaCl + H2O ; ΔH = -57 kJ mol-1


NaOH + CH3COOH -- > CH3COONa + H2O ; ΔH = -55 kJ mol-1


The value of the heat of neutralization for both processes are different because …..

a)

the ethanoic acid is less soluble in water.

b)

the production of sodium ethanoate salt absorbs heat.

c)

the ethanoic acid produces only a small amount of hydrogen ions.

d)

greater amount of heat is absorbed to ionize the ethanoic acid molecule.

9.

When 100 cm3 of 1.0 mol dm-3 of sodium hydroxide is added to 100 cm3 of 1.0 mol dm-3 of hydrochloric acid, temperature rises by 7 °C. Which of the following mixtures will produce an increment of 14 °C in temperature?

a)

50 cm3 of 1.0 mol dm-3 of sodium hydroxide 50 cm3 of 1.0 mol dm-3 of hydrochloric acid

b)

50 cm3 of 2.0 mol dm-3 of sodium hydroxide and 50 cm3 of 2.0 mol dm-3 of hydrochloric acid

c)

100 cm3 of 1.0 mol dm-3 of sodium hydroxide and 100 cm3 of 4.0 mol dm-3 hydrochloric acid

d)

200 cm3 of 1.0 mol dm-3 sodium hydroxide and 200 cm3 of 1.0 mol dm-3 hydrochloric acid

10.

The following thermochemical equation shows a combustion reaction between hexane. C6H14 and oxygen.


What is the mass of hexane need to be burnt to produce heat that can heat up 2 kg of water from 25 °C to 100°C?

[Relative atomic mass : C=12, H=l; specific heat capacity of water = 4.2 Jg-1 °C-1]

a)

5.16 g

b)

5.56 g

c)

15.48 g

d)

16.67 g

11.

The table shows the heat of combustion of three alcohols.



Which of the following factors increases the heat of combustion of alcohols?

a)

size of molecules decreases

b)

number of carbon atoms per molecule increases

c)

number of oxygen atoms per molecule increases

d)

number of hydrogen atoms per molecule decreases

12.

Diagram 15 shows the set-up of apparatus to determine heat of combustion of ethanol.


The heat of combustion of ethanol was found less than the theoretical value. What can be done to improve the experimental value?

a)

Remove the wooden block

b)

Use copper container to replace beaker

c)

Do not use wire gauze when heating

d)

Use greater volume of water

13.

Based on the following equation


(a) Mg(s) + H2SO4(aq) --------->.MgSO4(aq) + H2(g)

ΔH = - 467 kJ mol-1


the heat of reaction shows by symbol ΔH , sign negative shows....

a)

Endothermic reaction

b)

Exothermic reaction

14.

Based on the following equation


(a) Mg(s) + H2SO4(aq) --------->.MgSO4(aq) + H2(g)

ΔH = - 467 kJ mol-1


the heat of reaction shows by symbol ΔH , sign negative


choose the Energy level diagram for this reaction.

a)
b)
15.

based on the energy level diagram above choose the correct explanation.

a)

Energy content of the reactants is higher than the products

b)

Energy content of the products is higher than the reactants.

c)

the reaction is endothermic

16.

What is the meaning of heat of displacement.

a)

heat released when 1 mol of water is formed

b)

The heat released when one mole of a metal is displaced from its salt solution by a more electropositive metal.