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SN1 vs SN2

Total questions: 20

Worksheet time: 11mins

Name
Class
Date
1.

I think I understand this SN1 and SN2

a)

Yes, mostly

b)

Yes, partly

c)

No, not sure about most of it.

d)

Phew!!!Why did I opt for this subject?

2.

The bottom three pictures are a good way to represent a SN1 reaction progress.

a)

True

b)

False

3.

Which of these has only one transition state?

a)

SN1

b)

SN2

4.

Which of these has an intermediate state?

a)

SN1

b)

SN2

5.

Which of these is a one step reaction?

a)

SN1

b)

SN2

6.

Which of these is a two step reaction?

a)

SN1

b)

SN2

7.

In which reaction is an inverted product formed i.e. it is stereospecific?

a)

SN1

b)

SN2

8.

The other name for a reactant molecule in organic reactions is

a)

Substrate

b)

Superstrate

9.

The rate of SN2 reaction is controlled by

a)

The substrate only

b)

The nucleophile only

c)

Both substrate and nucleophile

10.

The rate of the SN1 reaction is controlled by

a)

The substrate only

b)

The nucleophile only

c)

Both the substrate and nucleophile

11.

Which of these is bimolecular?

a)

SN1

b)

SN2

12.

Which of these has two transition states?

a)

SN1

b)

SN2

13.

Which of the following is capable of influencing the rate of either of the SN1 or SN2 reactions?

a)

The bond strength between carbon and leaving group

b)

The nature of the substrate

c)

The nature of solvent

d)

The electron density of the nucleophile

14.

Tertiary carbons have more steric hinderance than secondary carbons

a)

Yes, always

b)

Yes, sometimes

c)

No, Never

15.

Primary carbocations have more positive inductive effect than secondary?

a)

Yes, always

b)

Yes, sometimes

c)

No, never

16.

Based on C-halogen bond strength in the table, the reaction with Iodine as the leaving group will be the slowest.

a)

True

b)

False

17.

Arrange the following Nucleophiles in the order of increasing reactivity. Water, Ammonia, Hydroxide ion and Cyanide ion

a)

Cyanide>hydroxide>ammonia>water

b)

water>ammonia>hydroxide>cyanide

c)

ammonia>water>cyanide>hydroxide

18.

Polar protic solvents stabilize the carbocation by hydrogen bonding and thus favor the SN1 mechanism.

a)

True

b)

False

19.

Aprotic solvents favor SN2 because they stabilize the transition state.

a)

True

b)

False

20.

Aprotic solvents cannot bond with the incoming nucleophile and this favors the SN2 mechanism.

a)

So True

b)

So False