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Electronic Spectroscopy

Total questions: 12

Worksheet time: 6mins

Name
Class
Date
1.

The electronic spectra in the visible range span is __________

a)

25000-72000 cm-1

b)

25000-50000 cm-1

c)

12500-25000 cm-1

d)

15000-30000 cm-1

2.

Which of the following transitions are of weak intensities and lie in the visible region?

a)

n→π*

b)

σ→σ*

c)

π→π*

d)

n→σ*

3.

Which of the following transitions are of weak intensities and lie in the visible region?

a)

n→π*

b)

σ→σ*

c)

π→π*

d)

n→σ*

4.

Which of the following transitions are of weak intensities and lie in the visible region?

a)

n→π*

b)

σ→σ*

c)

π→π*

d)

n→σ*

5.

Arrange the various electronic transitions in the order of increasing energy.

a)

n→σ* < π→π* < n→π* < σ→σ*

b)

n→π* < π→π* < n→σ* < σ→σ*

c)

n→σ* < n→π* < π→π* < σ→σ*

d)

σ→σ* < π→π* < n→π* < n→σ*

6.

Which of the following is not an auxochrome group?

a)

–OH

b)

–SH

c)

–OR

d)

–O2

7.

Which of the following shift leads to the decreased intensity of absorption?

a)

Hypochromic

b)

Hyperchromic

c)

Hypsochromic

d)

Bathochromic

8.

Increase in the intensity of absorp in UV-Visible spectrum is called

a)

Hypsochromic

b)

Bathochromic

c)

Hyperchromic

d)

Hypochromic

9.

An absorption towards longer wavelength is called

a)

Bathochromic shift

b)

Hypsochromic shift

c)

Hyperchromic shift

d)

Hypochromic shift

10.

An absorption towards shorter wavelength is called as

a)

Bathochromic shift

b)

Hypsochromic shift

c)

Hyperchromic shift

d)

Hypochromic shift

11.

Methane molecule show ------- electronic transition

a)

σ→σ*

b)

π→π*

c)

n→π*

d)

n→σ*

12.

In hyperchromic shift, extinction coefficient is

a)

Small

b)

Large

c)

No change

d)

None of the above