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Reactions of Alkanes

Total questions: 24

Worksheet time: 24mins

Name
Class
Date
1.

What is the condition needed for substitution reaction with chlorine?

a)

presence of sunlight

b)

presence of red light

c)

presence of UV light

d)

all of the above

2.

What type of chemical reaction is this:

C3H8 + Br2 ⟶ C3H7CBr + HBr

a)

Incomplete combustion

b)

Hydrogenation

c)

Complete combustion

d)

Free radical substitution

3.

Which of the following is true about incomplete combustion?

a)

It takes place because there is too much fuel

b)

It takes place because there is not enough supply of air

c)

The products are soot and hydrocarbons

d)

The products are hydrogen and water

4.

Give the name of reaction, when alkanes react with bromine in the presence of UV.

a)

Hydrogenation

b)

Halogenation

c)

Hydration

d)

Hydrohalogenation

5.

What happened if alkane reacts with limited oxygen?

a)

Produced carbon dioxide and water

b)

Produced carbon monoxide and water

c)

Produced oxygen and water

d)

Produced soot and water

6.

What is the name of this step?

a)

Termination Step

b)

Propagation Step

c)

Initiation Step

d)

Cleavage Step

7.

Which of the following shows a propagation step?

a)
b)
c)
d)
8.

What is the type of cleavage that occurs in the initiation step when a halogen is exposed to UV light?

a)

Heterolytic fission

b)

Hoholytic fission

c)

Homoterolytic fission

d)

Homolytic fission

9.

Which equation represents a termination step?

a)
b)
c)
d)
10.

Which equation is a propagation step in the conversion of chloromethane into dichloromethane by reaction with chlorine in the presence of ultraviolet light?

a)

CHCl3 + Cl2 ⟶ CCl4 + HCl

b)

●CH2Cl + ●Cl ⟶ CH2Cl2

c)

CH3Cl + ●Cl ⟶ CH2Cl2 + ●H

d)

●CH2Cl + Cl2 ⟶ CH2Cl2 + ●Cl

11.

Which species is produced in a propagation step during the reaction of propane with an excess of chlorine in the presence of UV light?

a)

H•

b)

C3H5Cl

c)

C3H7Cl

d)

C6H14

12.

Which one of the following is NOT a propagation reaction between methane and chlorine?

a)

CH4 + Cl• → CH3• + HCl

b)

CH3• + Cl• → CH3Cl + H•

c)

CH3• + Cl2 → CH3Cl + Cl•

d)

CH3Cl + Cl• → CH2Cl• + HCl

13.

Pick the CORRECT statement for the chlorination of alkane.

a)

The initiation step involves the attack of chlorine radicals on alkane

b)

Sunlight supplies energy for the breaking of C-H bonds in methane

c)

Chlorine radicals are produced by light catalysed fission

d)

Chlorine radicals are generated again in the termination step

14.

Which of the following is a free radical substitution reaction?

a)

A. Hydrolysis of alkanes

b)

B. Halogenation of alkanes

c)

C. Hydrogenation of alkanes

d)

D. Combustion of alkanes

15.

Propane, C3H8, undergoes incomplete combustion in a limited amount of air. Which products are most likely to be formed during this reaction?

a)

Carbon monoxide and water

b)

Carbon monoxide and hydrogen

c)

Carbon dioxide and hydrogen

d)

Carbon dioxide and water

16.

What is the mechanism of the reaction between ethane and chlorine in sunlight?

a)

Free radical substitution

b)

Free radical addition

c)

Electrophilic substitution

d)

Electrophilic addition

17.

Which step is this in the synthesis of chloroalkanes?

a)

Termination

b)

Initiation

c)

Propagation

d)

Position

18.

A particle with an unpaired electron:

a)

Ion

b)

Nucleophile

c)

Free Radical

d)

Neutrophile

19.

The following image is an example of:

a)

Elimination Reaction

b)

Free Radical Substitution Reaction

c)

Nucleophilic Substitution Reaction

d)

No reaction

20.

Which equation is a propagation step in the conversion of trichloromethane into tetrachloromethane by reaction with chlorine in the presence of ultraviolet light?

a)

CHCl3 + Cl2 ⟶ CCl4 + HCl

b)

●CCl3 + ●Cl ⟶ CCl4

c)

CHCl3 + ●Cl ⟶ CCl4 + ●H

d)

●CCl3 + Cl2 ⟶ CCl4 + ●Cl

21.

The function of uv in the reaction of alkane with bromine is to

a)

break the covalent bond between Br atoms.

b)

provide energy to start the reaction.

c)

start the heterolytic cleaveage.

d)

ease the reaction.

22.

Which of the following would have the highest boiling point?

a)

C3H8

b)

C4H8

c)

C5H12

d)

C22H44

23.

State the general formula for alkane

a)

CnH2n+2

b)

CnH2n

c)

CnH2n+1

d)

CnH2n-2

24.

What is the function of UV or heat during a free radical substitution reaction?

a)

To provide color for homolytic cleavage

b)

To provide energy for homolytic cleavage

c)

To provide color for heterolytic cleavage

d)

To provide energy for heterolytic cleavage