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Chapter 14 review

Total questions: 15

Worksheet time: 12mins

Name
Class
Date
1.

Which one of the following thermodynamic quantities is not a state function?

a)

Gibbs free energy

b)

enthalpy

c)

entropy

d)

work

2.

A system suffers an increase in internal energy of 80 J and at the same time has 50 J of work done on i

a)

+130 J

b)

+30 J

c)

-130 J

d)

-30 J

3.

All of the following have a standard heat of formation value of zero at 25oC and 1.0 atm except:

a)

N2(g)

b)

Fe(s)

c)

Ne(g)

d)

H(g)

4.

Thermodynamics

a)

ability to do work create heat

b)

the study of energy

c)

the study of heat flow

d)

the study of chemical

5.

Energy

a)

the ability to do work

b)

the energy available to do work

c)

the measure of the disorder of a system

d)

the thermal energy content of a system

6.

Exergy

a)

the energy available to do work

b)

the thermal energy content of a system

c)

the ability to do work

d)

the measure of the disorder of a system

7.

what are the three laws of thermodynamics

a)

The energy in the universe is constant

b)

Things get more disorganized over time in a system until everything is equal

c)

You can’t reach absolute zero

d)

You can reach absolute zero

8.

Kinetic energy

(a)  

9.

as temperature increases, the entropy of the system

a)

increases

b)

decreases

10.

three methods of heat transfer

a)

conduction

b)

kinetic energy

c)

radiation

d)

convection

11.

Which one of the following is an expression of the van't Hoff equation?

a)

ln K = - ΔHθ / RT + ΔSθ /R

b)

ΔH(T2) = ΔH(T1) + ΔCp(T2 - T1)

c)

ΔGθ = ΔHθ - TΔSθ

d)

ΔU = q + w

12.

Which one of the following statements describes a path function?

a)

A property of a system that depends only on the current state of the system, not on the path the system took to reach that state

b)

A property of a system that depends on the path taken between the initial and final states

c)

The sum of kinetic and potential energy contained in a substance

d)

The heat energy absorbed by a system at constant pressure

13.

Which of the following is true for a steady flow system?

a)

mass does not enter or leave the system

b)

mass entering can be more or less than the mass leaving

c)

mass entering = mass leaving

d)

none of the mentioned

14.

Which of the following statements is incorrect?

a)

When solid and liquid iron are in equilibrium, ΔG = 0.

b)

On going from solid copper to molten copper, ΔSo < 0.

c)

When a solid dissolves in a solvent, ΔsolHo may be positive or negative.

d)

For a phase change from liquid to vapour, Δvap H = ΔvapS × Tb where Tb = boiling point of the liquid.

15.

Which statement is incorrect about entropy?

a)

For a phase change, ΔS = 0.

b)

The value of So for a compound or element depends on temperature.

c)

The entropy of a system + surroundings increases during a spontaneous, irreversible process.

d)

A pure, perfect crystal has zero entropy at 0 K.