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Rotational spectroscopy

Total questions: 10

Worksheet time: 10mins

Name
Class
Date
1.

The different types of energies associated with a molecule are __________

a)

Vibrational energy

b)

electronic energy

c)

Rotational energy

d)

All of these

2.

Molecules which are having _______ are microwave active.

a)

Dipole moment

b)

High pressure Detector

c)

Principle axis

d)

Acidity

3.

A photon of wave number 100 cm-1 has a wavelength of

a)

1 m

b)

1 mm

c)

1000 nm

d)

100 m

4.

The photon described in Question 3 lies within which part of the electromagnetic spectrum?

a)

Radio wave

b)

Visible

c)

Infrared

d)

Ultraviolet

5.

The energy in joules of a photon of wavelength 355 nm is

a)

5.596 x 1019 J

b)

5.596 x 1028 J

6.

Calculate the moment of inertia, I, of the molecule 1H35Cl. The masses of the two atoms are mH = 1.673 x 1027 kg and mCl = 5.807 x 1026 kg. The equilibrium bond length of the molecule is 1.275 Å.

a)

2.644 x 1047 kg m2

b)

2.644 x 1027 kg m2

c)

2.644 x 1044 kg m2

d)

2.644 x 1024 kg m2

7.

Which of the following molecule has no rotational spectrum?

a)

NH3

b)

HCl

c)

N2

d)

H2O.

8.

The microwave active molecules are

a)

HCl, OCS

b)

CO,CO2

c)

Both a) and b)

d)

None of the above

9.

From the rotational microwave spectrum of 1H35Cl, we find that B = 10.59342 cm-1 . Given that the masses of 1H and 35 Cl are 1.0078250 and 34.9688527 amu, respectively, determine the bond length of the 1H35Cl molecule

a)

1.274 x 10-10 m

b)

1.674 x 10-10 m

c)

1.474 x 10-10 m

d)

1.0274 x 10-10 m

10.

The correct order of different types of energies is __________

a)

Eel >> Evib >> Erot

b)

Eel >> Erot >> Evib

c)

Evib >> Eel >> E rot

d)

None of these