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Photochemistry

Total questions: 15

Worksheet time: 11mins

Name
Class
Date
1.

This process promotes the molecule from the S0 to one of the vibration levels of the singlet excited states (S1, S2,..)

a)

Absorption of photon

b)

Emission of photon

c)

Fluorescence

d)

Vibrational relaxation

2.

(a)   fastest transition 10-15 s and it Starts from Ground level.

3.

Stark Einsteins law is applicable to

a)

Primary process

b)

secondary process

c)

chain termination process

d)

thermal reactions

4.

Quantum yield of a photo chemical reaction is always one.

a)

Agree

b)

Disagree

c)

May be

5.

Which of the following is a non-radiative transition

to a lower vibrational level within the same electronic state

a)

Internal conversion

b)

fluorescence

c)

inter system crossing

d)

vibrational relaxation

6.

Which of the following is a non-radiative transition between two electronic states of the same spin multiplicity.

a)

Internal conversion

b)

Inter-system crossing

c)

vibrational relaxation

d)

Phosphorescence

7.

Which of the following is a radiative transition between two electronic states of the same spin multiplicity and instantaneous process ?

a)

Phosphorescence

b)

fluorescence

c)

chemiluminescence

d)

photosensitization

8.

which one of the following is a non-radiative transition between two iso-energetic vibrational levels belonging to electronic states of different spin multiplicity

a)

Phosphorescence

b)

Inter-system crossing

c)

Fluorescence

d)

internal conversion

9.

____________ is a radiative transition between two electronic states of different spin multiplicity and occurs for a longer time even after the source is cut off.

a)

Fluorescence

b)

Phosphorescence

c)

Bio-luminescence

d)

Photo-sensitization

10.

(a)   is the number of molecules reacted divided by the number of photons absorbed by the system.

11.

Photochemical Combination of H2 with Cl2 has a high quantum yield because of following reasons. Multiple answers may be selected .

a)

Absorption of radiations in the first step involves production of atoms or free radicals, which initiate a series of chain reactions

b)

The active molecules may collide with other molecules and activate them

c)

Excited molecules may lose their energy by collisions with non-excited molecules

d)

Molecules may not receive sufficient energy to enable them to react

12.

What is the role of the uranyl ions added to oxalic acid solution in an chemical actinometer ?

a)

chain initiation

b)

photo sensitization

c)

catalyst

d)

reactant

13.

select the substance which is not a photosensitizer?

a)

Chlorine

b)

mercury

c)

Uranyl sulphate

d)

chlorophyll

e)

Silver bromide

14.

Can you identify the enzyme which is oxidized during Emission of light by fireflies ?

a)

Luciferin

b)

Papain

c)

Ficin

d)

Trypsin

15.

commercial analytical instruments used for Nitric oxide detection in air is based on reaction with ozone resulting in the formation of nitrogen dioxide in activated state . This technique is based on which of the following processes ?

a)

Photosensitization

b)

phosphorescence

c)

chemiluminescence

d)

Fluorescence