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Thermochemistry

Total questions: 15

Worksheet time: 1hrs 8mins

Name
Class
Date
1.

Calculate the amount of heat liberated from 366g of mercury when it cools from 77.0oC to 12.0oC. Specific heat of Hg = 0.140kJ/g*oC

(a)  

2.

A 12.1g piece of aluminum at 81.7oC is placed in a calorimeter containing water at 23.4oC. If the final temperature of the system is 24.9oC, what is the mass of the water? specific heat of Al = 0.900 J/g*oC; specific heat of water = 4.184 J/g*oC

(a)  

3.

Calculate the standard enthalpy change for the reaction :

2Al(s)+Fe2O3(s) --> 2Fe(s) + Al2O3(s)

given that:

2Al(s)+3/2O2(g) --> Al2O3(s) ΔHorxn=-1669.8kJ/mol

2Fe(s)+3/2O2(g) --> Fe2O3(s) ΔHorxn=-822.2kJ/mol

(a)  

4.

Calculate the enthalpy change for the reaction:

2C(graphite)+3H2(g)--> C2H6(g)

given that:

C(graphite)+O2(g) --> CO2(g) ΔHorxn= -393.5kJ/mol

H2(g)+1/2O2(g) --> H2O(l) ΔHorxn= -285.8kJ/mol

2C2H6(g)+7O2(g) --> 4CO2(g)+6H2O(l) ΔHorxn= -3119.6kJ/mol

(a)  

5.

Given the following data:

H2(g) --> 2H(g) ΔHorxn= 436.4kJ/mol

Br2(g) --> 2Br(g) ΔHorxn= 192.5kJ/mol

H2(g) + Br2(g) --> 2HBr(g) ΔHorxn= -72.4kJ/mol

Calculate ΔHorxn for

H(g) + Br(g) --> HBr(g)

(a)  

6.
Heat flows from _______ to ______ objects
a)
cooler to warmer
b)
warmer to warmer
c)
warmer to cooler
d)
cooler to cooler
7.
The transfer of thermal energy between objects of different temperatures is called...
a)
temperature
b)
heat
c)
internal energy
d)
none of these
8.

When thermal energy is added to a substance, the substance's particles move:

a)

More rapidly at an increased distance from each other.

b)

More rapidly with less distance between each other.

c)

More slowly with a greater distance between each other.

d)

More slowly with a reduced distance between each other.

9.
Heat transfer by conduction occurs when...
a)
particles bump into each other
b)
large numbers of atoms move from place to place
c)
atoms give off heat in the form of electromagnetic waves
d)
electromagnetic waves travel from place to place through a vacuum
10.
Heat transfer by convection occurs when...
a)
electrons bump into other electrons
b)
large numbers of atoms move from place to place
c)
atoms give off heat in the form of electromagnetic waves
d)
electromagnetic waves travel from place to place through a vacuum
11.
Thermal energy always moves:
a)
From a high temperature object to a lower temperature object.
b)
From a lower temperature object to a higher temperature object.
c)
From an object with lower kinetic energy to an object with higher kinetic energy.
d)
From an object of higher mass to an object of lower mass.
12.
A chemical reaction that absorbs heat from the surroundings is said to be __________ and has a __________ ΔH at constant pressure.
a)
endothermic; positive
b)
endothermic; negative
c)
exothermic; negative
d)
exothermic; positive
13.
Refer the the following question:
2N2 + 3H2 --> 2NH3 + 46 kJ
How much energy would be produced if only 1 mol of nitrogen was reacted?
a)
92 kJ
b)
0.143 kJ
c)
23 kJ
d)
15 kJ
14.
Do the reactants in an exothermic reaction have a higher or lower energy than the products?
a)
Higher
b)
Lower
15.

The diagram shows what happens when zinc reacts with hydrochloric acid. Which of these best describes the energy transformation that occurs during this reaction?

a)

Thermal energy - kinetic energy

b)

Kinetic energy -potential energy

c)

Chemical energy - thermal energy

d)

Potential energy - chemical energy