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Worksheets

Chemical

Total questions: 35

Worksheet time: 19mins

Name
Class
Date
1.

The nitro group is isoelectronic with

a)

Amines

b)

Amide

c)

Carboxylate anion

d)

Oxide ion

2.

Aromatic compounds with electron releasing substituents can be nitrated with

a)

Oleum

b)

Fuming nitric acid

c)

Dilute nitric acid

d)

Nitro acetate

3.

Streptomycin is used for curing

a)

Pneumonia

b)

Cancer

c)

Soar throat

d)

Tuberculosis

4.

Broad spectrum antibiotics are

a)

Penicillin

b)

Chloramphenicol

c)

Tetracycline

d)

Offloxacin

5.

Sulphanilamide is synthesized by

a)

Acetanilide is treated with chlorosulphuric acid, which on ammonolysis followed by hydrolysis with sodium hydroxide

b)

Acetanilide is treated with ammonia which on chlorosulphuric acid and sodium hydroxide

c)

p-acetamido benzene sulphonyl chloride on treatment with sodium hydroxide

d)

p-acetamido benzene sulphonyl chloride treated with 2-amino pyridine followed by hydrolysis with sodium hydroxide

6.

Drugs which decreases pain

a)

Codein

b)

p-acetamol

c)

Analgin

d)

Heroin

7.

Ibuprofen is used for treatment..........

a)

Treating pain, fever and inflammation

b)

Painful menstrual periods, migrains and rheumatoid arthritis

c)

To close a patent ducts artereasus in pre-mature baby

d)

To reduce dysentry and brain tumour

8.

Mepacrine is

a)

Anti pyrectic

b)

Antiacid

c)

Antimalaria

d)

Analgesic

9.

What are azidothymidines?

a)

Nucleotides

b)

Tuberculosis killer

c)

Reverse transcriptase inhibitor

d)

Activate transcriptase

10.

Antidepressants are

a)

To gain self-confidence

b)

To achieve efficiency in work

c)

Amphetamines are example

d)

Act as sedative

11.

Stimulants speeds up

a)

Cerebellum

b)

Lungs action

c)

Central nervous system

d)

Refluxs action

12.

Removal of hydrogen alpha- to carbon-oxygen double bond leads to

a)

Carbocation

b)

Enolate ion

c)

Carbonium ion

d)

Enamine

13.

Acid hydrolysis of acetoacetic ester gave

a)

Acetic acid

b)

Ethanoic acid

c)

Salt of acetate

d)

Acetic ester

14.

Acetoacetic ester exist in two tautomeric forms as evidenced by

a)

It gave reactions of ketone and phenol

b)

It gave reactions of phenol, double bond and ketone

c)

It gave reactions of aldehyde, phenol, ketone

d)

It gave reactions of aldehyde and ketones only

15.

Arndt-Eistert synthesis is

a)

Converting carboxylic acid into its acid chloride which on treatment with diazomethane followed by hydrolysis in presence of colloidal silver

b)

Converting carboxylic acid into its acid chloride which on treatment with diazomethane followed by hydrolysis in presence of sodium hydroxide

c)

Converting carboxylic acid into its ester which on treatment with diazomethane followed by hydrolysis in presence of colloidal silver

d)

Converting carboxylic acid into its acid chloride which on treatment with diazonium salt followed by hydrolysis in presence of colloidal silver

16.

Diazotisation of Ethyl ester of glycine taken as its hydrochloride with cold solution of sodium nitrite results

a)

Cyanoacetic Ester

b)

Acetoacetic Ester

c)

Diazo acetic ester

d)

Diazo methane

17.

N-nitroso-N-methyl urea on boiling with potassium hydroxide results

a)

Acetoacetic ester

b)

Diazomethane

c)

Potassium bicarbonate

d)

Methyl urea

18.

Diazomethane on reaction with phenol forms

a)

Ester

b)

Anisole

c)

Dimethyl ether

d)

Biphenyl

19.

Diazomethane on reaction with acid chloride followed by heating in presence of silver oxide gave

a)

Diazoketone

b)

Higher homologous carboxylic acid

c)

Lower homologous carboxylic acid

d)

Diazomethyl ketone

20.

Phenyl hydrazine is prepared by

a)

Reduction of benzene diazonium chloride with stannous chloride

b)

Reduction of benzene diazonium chloride with stannous chloride And concentrated hydrochloric acid

c)

Reduction of benzene diazonium chloride with stanic chloride and hydrochloric acid

d)

Reduction of benzene diazonium chloride with zinc and HCl

21.

Aniline can be prepared from phenyl hydrazine

a)

On reduction with zinc and hydrochloric acid

b)

On reduction with Fehling solution

c)

On reduction with SnCl2 and HCl

d)

On reduction with sodium and ethyl alcohol

22.

Phenol can be synthesized from diazonium salt by

a)

Heating an aqueous solution of diazonium salt

b)

Freezing an aqueous solution of diazonium salt

c)

Heating an aqueous solution of diazonium salt with potassium hydroxide

d)

Heating an aqueous solution of diazonium salt with zinc and HCl

23.

Hofmann ammonolysis method is suitable for

a)

Preparation of diamines, amino acids and aryl amine

b)

Preparation of diamines, alkyl amine

c)

Preparation of Quaternary ammonium salts

d)

Preparation of alkyl and aryl nitro compound

24.

Ter-butyl bromide on ammonolysis gave......... as major product

a)

Ter-butyl amine

b)

1-Butene

c)

Isobutylene

d)

Ter-butyl alcohol

25.

m-dinitrobenzene on reduction with borane in tetrahydrofuran as solvent leads to.........

a)

Diamino benzene

b)

Aniline

c)

m-nitro aniline

d)

No reaction

26.

Ketone in presence of hydrogen and ammonia under pressure in presence of Raney nickel as catalyst leads to

a)

Primary amine

b)

Secondary amine

c)

Tertiary amine

d)

Quaternary ammonium salts

27.

How direct nitration of aniline can be carried out?

a)

Using a mixture of concentrated nitric acid and concentrated sulphuric acid

b)

Using fuming nitric acid

c)

Amino group is protected and using nitrating mixture

d)

By using dilute nitric acid and dilute sulphuric acid

28.

Benzene diazonium salts react with aromatic compounds in alkaline medium. This reaction is known as

a)

Sandmeyer's reaction

b)

Gattermann-Bachman reaction

c)

Gomberg-Bachmann reaction

d)

Scheimann reaction

29.

When nitrobenzene is reduced with zinc and methanolic sodium hydroxide, the product obtained is

a)

Aniline

b)

Phenyl hydroxy amine

c)

p-amino phenol

d)

azobenzene

30.

O-nitrobenzaldehyde can be converted into o-aminobenzaldehyde by reacting with

a)

Lithium aluminium hydride

b)

Na/ethanol

c)

Stannous chloride and concentrated hydrochloric acid

d)

None of the above

31.

When primary amine reacts with chloroform in ethanolic KOH, the product formed is

a)

Aldehyde

b)

Cyanide

c)

Isocyanide

d)

An alcohol

32.

Furan reacts with ammonia in presence of alumina at 400 0C to give

a)

Pyridine

b)

Furfural

c)

Pyrrole

d)

Furoic acid

33.

Pyridine undergoes electrophilic substitution with fuming sulphuric acid at 350 0C to give

a)

3-pyridine sulphonic acid

b)

4-pyridine sulphonic acid

c)

2-pyridine sulphonic acid

d)

1-pyridine sulphonic acid

34.

Which of the following reagents react with furan to form 2-furan sulphonic acid

a)

SO2 in pyridine at 100 0C

b)

SO3 in pyridine at 100 0C

c)

Dilute sulphuric acid at 200 0C

d)

Dilute sulphuric acid at 100 0C

35.

Heating of succinic dialdehyde with ammonia results

a)

Thiophene

b)

Pyrrole

c)

Furan

d)

Pyridine