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UPS 3 SK015 SEMESTER I SESSION 2020/2021

Total questions: 20

Worksheet time: 30mins

Name
Class
Date
1.

Which of the following statements is NOT a statement of the Kinetic Molecular Theory?

a)

The unit for temperature is in Kelvin.

b)

Volume of gas molecules are negligible.

c)

The collisions between the gas particles are elastic.

d)

The volume occupied by a gas increases with temperature.

2.

Under what condition does hydrogen gas deviates from an ideal gas behaviour?

a)

Temperature : Low

Pressure : High

b)

Temperature : High

Pressure : Low

c)

Temperature : Low

Pressure : Low

d)

Temperature : High

Pressure : High

3.

At a fixed volume. The gas pressure in a vessel is 2.0 atm at 25 ⁰C. Find the pressure if it is heated to 250 ⁰C.

[Ideal gas constant, R = 8.314 J mol-1 K-1 ; R = 0.08206 L atm mol-1 K-1]

[Pressure : 1 atm = 760 mmHg = 760 torr = 101 325 Pa = 101 325 N m-2]

[Temperature 0 ⁰C = 273.15 K]

a)

1.14 atm

b)

3.51 atm

c)

20.0 atm

d)

35.1 atm

4.

A sample of gas exert 1000 torr of pressure at 333 K has the mass of 3.00 g. If the molar mass of the gas sample is 28 g/mol, calculate the volume occupied by this gas.

[Ideal gas constant, R = 8.314 J mol-1 K-1 ; R = 0.08206 L atm mol-1 K-1]

[Pressure : 1 atm = 760 mmHg = 760 torr = 101 325 Pa = 101 325 N m-2]

[Temperature 0 ⁰C = 273.15 K]

a)

2.23 L

b)

2.42 L

c)

22.3 L

d)

240 L

5.

A mixture of 40.0 g oxygen and 25.0 g nitrogen gas are placed in a closed vessel of 8.10 L at 25 ⁰C. Calculate the total pressure of the mixture.

[Ideal gas constant, R = 8.314 J mol-1 K-1 ; R = 0.08206 L atm mol-1 K-1]

[Pressure : 1 atm = 760 mmHg = 760 torr = 101 325 Pa = 101 325 N m-2]

[Temperature 0 ⁰C = 273.15 K]

a)

0.38 atm

b)

0.54 atm

c)

6.47 atm

d)

6.65 atm

6.

Which of the following statements is not true about gas?

a)

When the ideal gas molecules collide, there is no kinetic energy loss.

b)

Pressure exerted by the real gas is more than that of an ideal gas.

c)

The attractive forces between gas molecules for an ideal gas are negligible.

d)

At a constant pressure and number of mole, the volume occupied by an ideal gas is directly proportional to temperature.

7.

Under the same temperature and pressure, the particles in a sample of liquid ____________________________.

a)

have the same strength of intermolecular forces.

b)

have the same tendency to evaporate.

c)

have the same average kinetic energy

d)

have the same vapour pressure.

8.

Which of the following quantities is independant to the strength of attractive forces between liquid molecules?

a)

solubility

b)

surface tension

c)

viscosity

d)

vaporisation

9.
a)

I only

b)

I and II

c)

II and III

d)

I, II and III

10.
a)

I only

b)

I and II

c)

II and III

d)

I, II and III

11.

a)

solid

b)

liquid

c)

gas

d)

supercritical fluid

12.

a)

freezing, then condensation

b)

melting only

c)

sublimation only

d)

melting, then boiling

13.

a)

A, as concentration decreases

b)

B, as concentration decreases

c)

A, as concentration increases

d)

B, as concentration increases

14.

What is the Kc expression for this reaction?

2NO(g) + O2(g) ⇌ 2NO(g)

a)

Kc = [NO2]

[NO][O2]1/2

b)

Kc = [NO]2[O2]

[NO2]2

c)

Kc = [NO][O2]1/2

[NO2]

d)

Kc = [NO2]2

[NO]2[O2]

15.

What is the equilibrium constant, Kc expression for reaction

Fe3O4(s) + 4H2(g) ⇌ 3Fe(s) + 4H2O(g)

a)

[Fe]3 [H2O]4

[Fe3O4] [H2]4

b)

[H2O]4

[H2]4

c)

[Fe3O4] [H2]4

[Fe]3 [H2O]4

d)

[H2]4

[H2O]4

16.

At 830 °C, the value of Kp for the equilibrium

2SO2 (g) + O2 (g) ⇌ 2SO3 (g)

is 0.13. What is the value of Kp for

2SO3 (g) ⇌ 2SO2 (g) + O2 (g)

a)

0.36

b)

2.8

c)

7.7

d)

59

17.

The following reaction

SO2 (g) + NO2 (g) ⇌ SO3 (g) + NO (g)

had reached a state of equilibrium. It was found to contain 0.15 mol L-1 of NO2 , 0.20 mol L-1 of SO2, 0.40 mol L-1 of SO3 , and 0.30 mol L-1 of NO. Calculate the equilibrium constant, Kc for this reaction.

a)

4.0

b)

0.40

c)

0.25

d)

2.5

18.

The equilibrium constant, Kp for the reaction

2NO2(g) ⇌ 2NO(g) + O2(g)

is 158 at 1000 K. Calculate PO2 if PNO2= 0.400 atm and PNO= 0.270 atm.

a)

867 atm

b)

234 atm

c)

346 atm

d)

72 atm

19.

The reaction

HCOOH(g) ⇌ CO(g) + H2O(g)

has Kp = 1.6 x 106 at 673 K. Calculate the value of Kc for the reaction at this temperature.

[Ideal gas constant, R = 0.08206 L atm mol-1 K-1]

a)

5.2 x 102

b)

2.9 x 104

c)

8.8 x 107

d)

2.2 x 105

20.

At the start of reaction, there are 0.0711 M of N2, 9.17 x 10-3 M of H2, and 1.83 x 10-4 M of NH3 in 3.5 L reaction vessel at 375 °C. If the equilibrium constant, Kc for the reaction

N2(g) + 3H2(g) ⇌ 2NH3(g)

is 1.2 at this temperature, calculate Qc and predict the direction that the net reaction will shift to reach equilibrium.

a)

1.64, shift to the right

b)

1.64, shift to the left

c)

0.611, shift to the right

d)

0.611, shift to the left