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FIVIZZ: ROAD TO MIDSEM - CHEMISTRY 3

Total questions: 15

Worksheet time: 12mins

Name
Class
Date
1.

What is the effect of catalyst on a reversible reaction?

a)

Catalyst increases the product of a reaction

b)

Catalyst increases the equilibrium constant

c)

Catalyst increases the rate of the forward reaction

d)

Catalyst increases both the rate of forward and reverse reaction

2.

 CaCO3(s)  CaO (s) + CO2(g)CaCO_3\left(s\right)\ ⇋\ CaO\ \left(s\right)\ +\ CO_2\left(g\right)  
The equilibrium constant,  KpK_p  for the above reaction is 319 Pa at 298 K and,  1.8×1051.8\times10^5  Pa at 5500 K. Hence, it can be concluded that,

a)

the forward reaction is endothermic

b)

the value of  KpK_p  depends on the amount of the  CaCO3CaCO_3  used

c)

increasing pressure will increase the yield of  CO2CO_2  

d)

the amount of  CO2CO_2  produced is not affected by temperature

3.

Which of the following will decrease the  KcK_c  for an exothermic reaction?

a)

Increase the temperature

b)

Increase the pressure

c)

Increase the amount of catalyst used

4.

The dissociation constant for an organic acid, HA is 1.4×105 1.4\times10^{-5\ }  M. Calculate the concentration of  H3O+H_3O^+  ion in 0.01 M HA.

a)

 1.13×1031.13\times10^3  M

b)

 2.81×1032.81\times10^{-3}  M

c)

 3.74×1043.74\times10^{-4}  M

d)

 51.40×10751.40\times10^{-7}  M

5.

The degree of dissociation of a weak acid, HA at pH 2.0 is 0.02. What is the value of  KaK_a   for HA?

a)

 1.0×105 mol dm31.0\times10^{-5}\ mol\ dm^{-3}  

b)

 2.0×104 mol dm32.0\times10^{-4}\ mol\ dm^{-3}  

c)

 3.0×105 mol dm33.0\times10^{-5}\ mol\ dm^{-3}  

d)

 5.0×104 mol dm35.0\times10^{-4}\ mol\ dm^{-3}  

6.

In which of the following reaction,  OHOH^-  acts as a conjugate base?

a)

 HCO3 + H2O  H2CO3 + OHHCO_3^-\ +\ H_2O\ ⇋\ H_2CO_3\ +\ OH^-  

b)

 HSO3 + H2O  H2SO3 + OHHSO_3^-\ +\ H_2O\ ⇋\ H_2SO_3\ +\ OH^-  

c)

 HNO3 + OH  NO3 + H2OHNO_3^-\ +\ OH^-\ ⇋\ NO_3^-\ +\ H_2O  

7.

Pick the correct statement(s) about salt hydrolysis.

a)

Salt hydrolysis occurs when there is reaction between cations or anions with water

b)

The salt is basic when cations undergo hydrolysis

c)

The salt is acidic when anions undergo hydrolysis

8.

The degree of dissociation of ethanoic acid in liquid ammonia is higher than water. Explain why.

a)

Ethanoic acid is more soluble in liquid ammonia than in water

b)

Ammonia is more polar than water

c)

Ammonia is a stronger acid than water

d)

Ammonia is a stronger base than water

9.

If  500 cm3500\ cm^3  2.0 M HCl is mixed with  1500 cm31500\ cm^3  0.5 M HCl, determine the concentration of the mixture.

a)

0.750 M

b)

0.875 M

c)

1.250 M

d)

2.500 M

10.

The critical temperature of a substance is

a)

the temperature below which it cannot exist as liquid

b)

the temperature below which it cannot be supercooled

c)

the temperature above which it cannot be vapourised

d)

the temperature which is always lower than that triple point temperature

11.

Sucrose is an example of a non-volatile and non-ionising solute in water. Calculate the vapour pressure lowering, at 27   , of a solution of 75.0 grams of sucrose,  C12H22O11C_{12}H_{22}O_{11}  dissolved in 180 g of water. The vapour pressure water at 27    is 26.7 torr. Assume the solution is ideal.

a)

0.571 torr

b)

0.585 torr

c)

0.058 torr

d)

0.548 torr

12.

The boiling point of a liquid depends on

a)

its purity

b)

the external atmospheric pressure

c)

the volume of the container used

13.

The standard enthalpy of combustion of C is -393  kJ mol1kJ\ mol^{-1}  . Choose the correct value of enthalpy for the reaction,

 2C (s) + 2O2 (g)  2CO2 (g)2C\ \left(s\right)\ +\ 2O_2\ \left(g\right)\ \rightarrow\ 2CO_2\ \left(g\right)  

a)

-393 kJ

b)

+393 kJ

c)

-786 kJ

d)

+786 kJ

14.

What mass of methane must be burned to raise 2.00 kg of water at 20   to 100    ? ( CwaterC_{water}  =  4.18 J g1 K14.18\ J\ g^{-1}\ K^{-1}  ,  ΔHc \Delta H_{c\ } for methane = -890  kJ mol1kJ\ mol^{-1}  )

a)

12.0 g

b)

13.5 g

c)

120 g

d)

135 g

15.

When X element combines with Y element, the ionic compound XY formed is very stable if

a)

X has a low ionisation energy

b)


YY^- is small

c)

The lattice energy of XY is very endothermic