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Trial UPS Chapter 1: Reaction Kinetics

Total questions: 20

Worksheet time: 16mins

Name
Class
Date
1.

The reaction A + 2B → products was found to have the rate law, k = k[A][B]2. Predict by what factor the rate of reaction will increase when the concentration of B is doubled and the concentration of A remained uncanged

a)

2

b)

4

c)

6

d)

8

2.

The catalyst alters the rate of a chemical reaction by,

a)

providing an alternative pathway with a lower Ea

b)

changing the products formed in the direction of the reaction

c)

providing a surface on which the molecules react

d)

increasing the frequencies of collisions between molecules

3.

The overall order for the reaction,

2A + B → C

is one and with respect to B the order is zero. Which of the following statements is true?

a)

The rate law of the reaction is rate =k[A]2[B]

b)

The formation of C is double the appearance of A

c)

The rate of reaction would increase with increasing concentration B

d)

The half-life of the reaction is independent on the concentration of the reactants

4.
Under the collision theory, the particles must collide with  ____ and ____ for a reaction to occur.
a)
sufficient rate and sufficient energy
b)
sufficient surface area and correct orientation
c)
sufficient catalyst and sufficient energy
d)
sufficent energy and correct orientation
5.
Which of the following is NOT a factor affecting reaction rate?
a)
temperature
b)
catalysts
c)
particle size
d)
polarity
6.
Why does a higher temperature increase the rate of a reaction?
a)
it increases both the frequency and energy of particle collisions
b)
it only increases the frequency of particle collisions
c)
it only increases the energy of particle collisions
d)
it reduces the activation energy of the reaction
7.
A possible rate law for a third overall order of a reaction is __________________
a)
Rate = k [A]2[B]2
b)
Rate = k [A][B]3
c)
Rate = k [A]3 [B]
d)
Rate = k [A]2[B]
8.

What is the unit for rate constant,K if rate law:

Rate = K [A]

a)

s-1

b)

M s-1

c)

M-1 s-1

d)

M-2 s-1

9.

Given the chemical equation, Haber Prosess

N2(g) + 3H2 (g) --> 2NH3 (g)


Based on this reaction, first order for concentration N2 and zero order for concentration H2.


Write rate law:

a)

Rate = K [N2]1 [H2]1

b)

Rate = K [N2]1

c)

Rate = K [H2]0

d)

Rate = K [N2]1 [H2]3

10.
Which one of the following is a first order, overall reaction
a)
k1= 1.000 M s-1
b)
k1= 5403.2 M½ s½
c)
k1= 1.23 x 10-6 M-1 s-1
d)
k1= 10.7 s-1
11.
Consider the following rate law: Rate = k[A]n[B]m
How are the exponents n and m determined?
a)
by using balanced chemical equation
b)
By using the subscripts for the formulas
c)
By educated guess
d)
By experiment 
12.

Given the following balanced equation :

2NO(g) + Cl2(g) → 2NOCl(g)

If the rate of disappearance of Cl2 is 4.84 x 10-2 Ms-1, what is the rate of disappearance of NO?

a)

1.45 x 10-2 Ms-1

b)

2.42 x 10-2 Ms-1

c)

3.67 x 10-2 Ms-1

d)

9.68 x 10-2 Ms-1

13.

What happened to the rate of reaction, if concentration of reactant is 'zero order'.

a)

rate of reaction will become double

b)

rate of reaction will become triple

c)

rate of reaction will become quadrapel

d)

No affect to the rate of reaction

14.

Given 3A + B -> 2C


Which statement is TRUE

a)

Concentration A will be increase and concentration B will be decrease after reaction.

b)

Concentration A will be increase and concentration C will be decrease after reaction.

c)

Concentration B will be decrease and concentration C will be increase after reaction.

d)

Concentration B will be decrease and concentration A will be increase after reaction.

15.

Determine the value of rate constant, K based on this table


Rate = K [Q]2

a)

1.0 M-1 s-1

b)

2.0 M-1 s-1

c)

3.0 M-1 s-1

d)

4.0 M-1 s-1

16.

Which of the graph refer for this chemical reaction:


2Q (g) ---> R (g)

a)
b)
c)
d)
17.

The graph the rate of reaction below, refer to the:

a)

zero order

b)

first order

c)

second order

d)

third order

18.

Which of the graph, half life for zero order

a)
b)
c)
d)
19.

Which of the temperature condition can be affected rate of reaction become increase?

a)

In ice bath

b)

In tap water

c)

In water bath

d)

In water pool

20.

Which statement will be increase the rate of reaction

a)

Temperature must be lowered

b)

Dilute concentration

c)

Lower pressure

d)

Smaller size particles