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d Block Metals II

Total questions: 12

Worksheet time: 7mins

Name
Class
Date
1.

Here are some electron configurations:

1) Cu = [Ar] 3d94s2

2) Cr = [Ar] 3d54s1

3) Mn2+ = [Ar] 3d5

Which ones are correct?

a)

1 and 3 only

b)

2 only

c)

2 and 3 only

d)

1, 2 and 3

2.

Aqueous Fe3+ ions are reacted with an excess of aqueous sodium hydroxide. What is the product formed ?

a)

[Fe(OH)6]3-

b)

Fe(OH)3(H2O)3

c)

[Fe(OH)4(H2O)2]-

d)

[Fe(OH)4]3-

3.

VO2+ ions can be reduced to V2+ ions using zinc metal in aqueous solution. In addition to VO2+, how many coloured ions containing vanadium are produce over the course of the reduction reactions?

a)

one

b)

two

c)

three

d)

four

4.

Which of the following is the electron configuration of a d-Block element?

a)

1s22s22p63s23p63d104s24p5

b)

1s22s22p63s23p63d84s2

c)

1s22s22p63s23p6

d)

1s22s22p63s23p63d104s24p65s1

5.

Which of the following compounds contains elements from each of the s, p and d blocks of the periodic table?

a)

KAl(SO4)2

b)

CuCrO4

c)

KMnO4

d)

Na2B4O7

6.

Cu2+ ions can form a complex ion with Cl- ions and also with NH3.

These complex ions have

a)

different shapes but the same colour

b)

different shapes and different colours

c)

the same shape and the same colour

d)

the same shape but a different colour

7.

Cr3+ ions form a complex ion with both ammonia and with hydroxide ions. These complex ions have:

a)

a different charge but the same coordination number

b)

a different charge and a different coordination number

c)

the same charge and the same coordination number

d)

the same charge but a different coordination number

8.

[Cr(NH2CH2CH2NH2)3]3+ is a complex ion which forms optical isomers.

Which of the following statements is/are true?

1: NH2CH2CH2NH2 is a bidentate ligand

2: The complex has an octahedral shape

3: The terms cis and trans are used to describe the optical

isomers

a)

1, 2 and 3

b)

1 and 2 only

c)

1 and 3 only

d)

1 only

9.

What is the overall charge on the complex ion hexacyanoferrate(II) ?

a)

2+

b)

3-

c)

4-

d)

1-

10.

Which of these is the correct name of the catalyst for the oxidation of sulphur dioxide in the Contact Process?

a)

vanadium oxide

b)

vanadium pentoxide

c)

divanadium oxide

d)

iron

11.

Which of the following complex ions have roughly the same colour?

a)

[Cr(H2O)6]3+. and Fe(H2O)6]3+

b)

[CuCl4]- and [Cu(H2O)6]2+

c)

[Mn(H2O)6]2+ and [Co(H2O)6]2+

d)

Fe(H2O)6]2+. and. [V(H2O)6]2+

12.

What is the shape and colour of the [CuCl4]- complex ion?

a)

square-planar and green

b)

square planar and yellow

c)

tetrahedral and blue

d)

tetrahedral and yellow