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IB Chemistry Energetics SL

Total questions: 18

Worksheet time: 36mins

Name
Class
Date
1.

When 100 cm3 of 1.0 mol dm–3 HCl is mixed with 100 cm3 of 1.0 mol dm–3 NaOH, the temperature of the resulting solution increases by 5.0 °C. What will be the temperature change, in °C, when 50 cm3 of these two solutions are mixed?

a)

2.5

b)

5.0

c)

10

d)

20

2.

Which statement about bonding is correct?

a)

Bond breaking is endothermic and requires energy.

b)

Bond breaking is endothermic and releases energy.

c)

Bond making is exothermic and requires energy

d)

Bond making is endothermic and releases energy.

3.

Consider the following reactions.

Cu2O(s) + O2(g) → 2CuO(s) ∆HO = –144 kJ

Cu2O(s) → Cu(s) + CuO(s) ∆HO = +11 kJ

What is the value of ∆HO, in kJ, for this reaction?

Cu(s) + O2(g) → CuO(s)

a)

–144 + 11

b)

+144 – 11

c)

–144 – 11

d)

+144 + 11

4.

Consider the two reactions involving iron and oxygen.

2Fe(s) + O2(g) → 2FeO(s) ∆HO = –544 kJ

4Fe(s) + 3O2(g) → 2Fe2O3(s) ∆HO = –1648 kJ

What is the enthalpy change, in kJ, for the reaction below?

4FeO(s) + O2(g) → 2Fe2O3(s)

a)

–1648 – 2(–544)

b)

–544 – (–1648)

c)

–1648 – 544

d)

–1648 – 2(544)

5.

Which processes have a negative enthalpy change?

I. 2CH3OH(l) + 3O2(g) → 2CO2(g) + 4H2O(l)

II. HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)

III. H2O(g) → H2O(l)

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

6.

Which equation represents the bond enthalpy for the H–Br bond in hydrogen bromide?

a)

HBr(g) → H(g) + Br(g)

b)

HBr(g) → H(g) + Br(l)

c)

HBr(g) → H(g) + Br2(1)

d)

HBr(g) → H(g) + 1/2Br2(g)

7.

Which types of reaction are always exothermic?

I. Neutralization

II. Decomposition

III. Combustion

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

8.

A pure aluminium block with a mass of 10 g is heated so that its temperature increases from 20 °C to 50 °C . The specific heat capacity of aluminium is 8.99 × 10–1 J g–1 K–1. Which expression gives the heat energy change in kJ?

a)

10 × 8.99 × 10–1 × 303

b)

10 × 8.99 × 10–1 × 30

c)

(10 × 8.99 × 10–1 × 303)/1000

d)

(10 × 8.99 × 10–1 × 30)/1000

9.

Which statement is correct given the enthalpy level diagram below?

a)

The reaction is endothermic and the products are more thermodynamically stable than the reactants.

b)

The reaction is exothermic and the products are more thermodynamically stable than the reactants.

c)

The reaction is endothermic and the reactants are more thermodynamically stable than the products.

d)

The reaction is exothermic and the reactants are more thermodynamically stable than the products.

10.

Identical pieces of magnesium are added to two beakers, A and B, containing hydrochloric acid.

Both acids have the same initial temperature but their volumes and concentrations differ.

Which statement is correct?

a)

he maximum temperature in A will be higher than in B.

b)

The maximum temperature in A and B will be equal.

c)

It is not possible to predict whether A or B will have the higher maximum temperature.

d)

The temperature in A and B will increase at the same rate.

11.

The specific heat of iron is 0.450 J g–1 K–1. What is the energy, in J, needed to increase the temperature of 50.0 g of iron by 20.0 K?

a)

9.00

b)

22.5

c)

45.0

d)

450

12.

Consider the reaction between magnesium and hydrochloric acid. Which factors will affect the reaction rate?

I. The collision frequency of the reactant particles

II. The number of reactant particles with E ≥ Ea

III. The number of reactant particles that collide with the appropriate geometry

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

13.

Use the average bond enthalpies below to calculate the enthalpy change, in kJ, for the following reaction.

H2(g) + I2(g) → 2HI(g)

a)

+290

b)

+10

c)

-10

d)

-290

14.

Which equation represents the reaction for which the enthalpy change, ΔH, is the mean bond energy of the C-F bond?   

a)

CF4(g) → C(g) + 4F(g)

b)

¼CF4(g) → ¼C(g) + F(g)

c)

C(g) + 4F(g) → CF4(g)

d)

¼C(g) + F(g) → ¼CF4(g)

15.

Consider the bond enthalpy values in the table.

For the reaction

H-O-O-H(g) \rightarrow H-O-H(g) + 1/2 O=O(g)

the enthalpy change, in kJ mol−1, is

a)

-102

b)

+102

c)

+350

d)

+394

16.

Using the data in the table below, calculate the standard enthalpy change, in kJ mol−1, for the reaction between carbon disulfide, CS2, and oxygen shown in the following equation.

CS2(g) + 3O2(g) → CO2(g) + 2SO2(g)

a)

-570

b)

-790

c)

-860

d)

-1080

17.

When 10 cm3 of 2 mol dm−3 hydrochloric acid is reacted with 10 cm3 of 2 mol dm−3 sodium hydroxide solution, the temperature change is ΔT.

HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)

When the reaction is repeated with 50 cm3 of each solution, the temperature change is

a)

ΔT

b)

5 x ΔT

c)

1/5 x ΔT

d)

10 x 2 x ΔT

18.

In an endothermic reaction in aqueous solution, which of the following is correct?

a)

A

b)

B

c)

C

d)

D