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HIgher CIS knowledge check

Total questions: 16

Worksheet time: 1hrs 20mins

Name
Class
Date
1.

Use the information in your databook to calculate the enthalpy change for the following reaction:

H2(g) + Cl2(g) --> 2HCl(g)

a)

172

b)

200

c)

-185

d)

450

2.

1. 0.22g of propane (C3H8) was used to heat 200cm3 of water. The temperature of water was raised by 35oC. Calculate the enthalpy of combustion of propane.

a)

-5852

b)

-3218

c)

2297

d)

3456

3.

Use Hess's Law to calculate the enthalpy of combustion of methane

a)

- 891 KJ mol-1

b)

- 605 KJ mol-1

c)

- 1041 KJ mol-1

d)

- 1435 KJ mol-1

4.
For the reaction...
SO2 + O2  <=>  SO3
If the concentration of SO2 is increased, the equilibrium position of the reaction will shift ___________.
a)
to the left
b)
to the right
c)
to the left and right 
d)
neither left nor right
5.
For the reaction...
N2 (g) +  3 H2 (g) <=> 2 NH3 (g)

If the pressure in the system is increased,  which substance(s) will increase in concentration?
a)
N2  (as 2 mol gas  → 4 mol gas)
b)
H2 (as 2 mol gas  → 4 mol gas)
c)
N2 and H2 (as 2 mol gas  → 4 mol gas)
d)
NH3 (as 4 mol gas  → 2 mol gas)
6.
For the reaction...
N2  +  O2  <=>  2NO:  Δ H = +182 kJ mol-1.
If the temperature is increased the equilibrium position will shift _______.
a)
to the left
b)
to the right
c)
to the left and right
d)
neither left nor right
7.

When reacting Na with Cl2, we calculated that the theoretical yield should be 13 grams. Our actual yield was 12.5 grams. What is the percent yield?

a)

90.4%

b)

104%

c)

96.15%

d)

1.04%

8.
CH4  +  2O2  →  CO2  +  2H2O
24 grams of CH4 was added to the above reaction. Calculate the theoretical yield of CO2.
a)
66 grams
b)
132 grams
c)
33 grams
d)
8.72
9.

2Fe2O3 + C → Fe + 3CO2

You add 28 grams of carbon. You find the actual yield to be 181.2 grams of CO2. What is the percent yield of CO2? (Hint: calculate theoretical yield of CO2 first)

a)

58.83%

b)

308%

c)

6435%

d)

15.5

10.

Use the equation 2 Al + 3 Cl2 ---> 2 AlCl3. If 2 moles of aluminum and 2 moles of chlorine are reacted, identify the limiting reactant.

a)

AlCl3

b)

Cl2

c)

Al

11.
Which of the following half reactions correctly represents a reduction half reaction?
a)
Fe →Fe2+ + 2e-
b)
Pb4+ + 2e- →Pb2+
c)
2O-2 →O2 + 4e-
d)
Fe + 3e- →Fe3+
12.
I have 25mL of 1M HCl which neutralises 20mL of NaOH. What is the concentration of the NaOH?
a)
0.8 M
b)
1 M
c)
1.25 M
13.

C6H8O7 + 3NaOH → C6H5O7Na3 + 3H2O


Calculate the percentage atom economy for the production of sodium citrate, C6H5O7Na3.

a)

82.7%

b)

90%

c)

93.5%

14.

In a redox titration with potassium permanganate, no indicator was added, why?

a)

a pH meter is used

b)

It is a self-indicating reaction

15.

In a redox titration, what is the purpose of adding concentrated sulphuric acid to the reaction mixture?

a)

to increase the pH

b)

to provide H+ ions

c)

to slow down the reaction

d)

to heat it up

16.

This chromatogram from a gas chromatography shows that there is a higher concentration of sucrose than glucose

a)

true

b)

false