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UJIAN PENILAIAN SUMATIF 2 (DK024)- TRIAL

Total questions: 20

Worksheet time: 40mins

Name
Class
Date
1.

The correct IUPAC name for this compound is

a)

trans-2,3,4-terimethyl-3-hexene

b)

cis-2,3,4-trimethyl-3-hexene

c)

trans-2,3,4-trimethyl-2-hexene

d)

cis-2,3,4-trimethyl-2-hexene

2.

Choose the most stable alkene that obeys Saytzeff's rule.

a)

CH3CH=CHCH3

b)

(CH3)2C=C(CH3)2

c)

CH3CH=CH2

d)

(CH3CH2)CH=CHCH3

3.

The conversion above can be carried out using

a)

Hot acidified KMnO4

b)

H2O in dilute H2SO4

c)

cold alkaline KMnO4

d)

Hot concentrated H2SO4

4.

The mechanism for the following sequence of reactions is

a)

Electrophilic addition reaction

b)

Nucleophilic addition reaction

c)

Electrophilic substitution reaction

d)

Nucleophilic substitution reaction

5.

An organic compound P undergo hydrogenation reaction. P also reacts with HCl to form 2-chlorobutane. Determine the structure of P.

a)

CH3CH2CH=CH2

b)

CH3C(CH3)=CH2

c)

CH3CH=CH2

d)

CH3CH2CH(OH)CH3

6.

Which of the following reagents can be used to distinguish between alkane and alkene?

a)

Hydrogen gas with a nickel catalyst

b)

Chlorine water

c)

Br2 in CH2Cl2 in the dark

d)

Hot acidified potassium permanganate

7.

Which of the following is NOT possibly an alkene?

a)

C2H2

b)

C4H8

c)

C4H6

d)

C6H8

8.

Several reagents were reacted with 2-methyl-2-pentene. Which of the following products is NOT correct?

a)

Reagents: H2 with Platinum catalyst

Product: 2-methylpentane

b)

Reagents: Aqueous Bromine

Product: 3-bromo-2-methyl-2-pentanol

c)

Reagents: H2O in dilute H2SO4

Product: 2-methyl-2-pentanol

d)

Reagents: HBr in CH3OOCH3

Product: 2-bromo-2-methylpentane

9.

Choose reaction(s) that follow(s) Markovnikov's rule.

a)

I only

b)

I and II

c)

II and III

d)

I, II and III

10.

What is the name of the following alkene?

a)

2,2-dichloro-6-methylcyclohexene

b)

3,3-dichloro-1-methylcyclohexene

c)

5,5-dichloro-1-methylcyclohexene

d)

1,1-dichloro-3-methyl-2-cyclohexene

11.

Which of the following statements about alkenes is NOT true?

a)

They are unsaturated hydrocarbons

b)

They undergo addition reaction

c)

They can be attacked by electrophiles

d)

They all have the general formula of CnH2n

12.

Which reagent below will NOT attack 2-pentene?

a)

Hydrogen chloride, HCl

b)

Cl2 in CH2Cl2

c)

Cyanide ion, CN-

d)

Hydrogen ion, H+

13.

The correct structural formula for m-isopropylbenzaldehyde is

a)
b)
c)
d)
14.

The product which is formed in the following reaction is

a)
b)
c)
d)
15.

How many delocalised π electrons must a planar and cyclical unsaturated hydrocarbon have if it is aromatic?

a)

4

b)

8

c)

10

d)

12

16.

When benzene is treated with a nitrating mixture, nitrobenzene is formed.

Which of the following statements is CORRECT concerning nitration?

a)

Nitration of benzene proceeds by electrophilic addition.

b)

Nitration of benzene proceeds by a free radical mechanism.

c)

The electrophile that attacks by the benzene ring is the NO2+ ion.

d)

The electrophile that attacks by the benzene ring is NO2 molecule.

17.

Why does benzene undergo substitution reactions rather than addition reactions?

a)

Benzene is a planar, aromatic compound.

b)

All the carbon atoms in benzene is sp2 hybridised.

c)

All the carbon-carbon bonds in benzene are strong.

d)

Benzene has extra stability due to the delocalized π electrons.

18.

Which of the following structures follow Huckel’s rule?

a)
b)
c)
d)
19.

The following reaction is known as

a)

Friedel-Crafts alkylation

b)

Friedel-Crafts acylation

c)

Nucleophilic substitution

d)

Electrophilic addition

20.

Bromination of benzene is carried out using iron(III) bromide, FeBr3 as a catalyst. The function of FeBr3 in this reaction is to produce..... ?

a)

Bromide free radicals

b)

Bromide ions

c)

Nucleophile

d)

Electrophile