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S1-Q4-U4 - L1 all

Total questions: 15

Worksheet time: 1hrs 16mins

Name
Class
Date
1.

Given the following data: ΔHf[FeO(s)] = –270kJmol–1

ΔHf [Fe2O3(s)] = –820 kJ mol–1

Select the expression which gives the enthalpy change, in kJ mol–1, for the reaction:

2FeO(s) + 1⁄2O2(g) → Fe2O3(s)

a)

–140

b)

–1090

c)

–280

d)

+280

e)

–550

2.
The standard enthalpy changes of formation of iron(II) oxide, FeO(s), and aluminium oxide, Al2O3(s), are –266 kJ mol–1 and –1676 kJ mol–1 respectively.
What is the enthalpy change under standard conditions for the following reaction?
3FeO(s) + 2Al (s)   ->   3Fe(s) + Al2O3(s) 
a)
+878kJ 
b)
–878kJ 
c)
–1942kJ 
d)
–2474kJ 
3.
C2H4(g) + H2(g)   ->   C2H6(g)  ∆H°=-137 kJ mol-1
Which statement about this information is correct?
a)
The total energy of the bonds broken in the reactants is greater 
than the total energy of the bonds 
formed in the product 
b)
The bonds broken and the bonds made are of the same strength 
c)
The total energy of the bonds broken in the reactants is less than the total energy of the bonds formed in the product 
d)
No conclusion can be made about the sums of the bond enthalpies in the product compared with the reactants 
4.

Ethene and iodine react to form 1,2-diiodoethane. The equation for this reaction is shown, the total energy change per mole of ethene is (-24 KJ/mol) if the bond energies are [C-C is 346 ; C=C is 602 ; C-H is 411 ; I-I is 148] , calculate the bond energy of C-I ??

a)

2031 KJ

b)

387 KJ

c)

214 KJ

d)

598.5 KJ

5.

Which of the following hydrogen halides has the smallest bond enthalpy?

a)

HF

b)

HCl

c)

HBr

d)

HI

6.

Chloromethane is produced by the reaction of methane CH4 with chlorine gas in the presence of UV light. The equation for this reaction is shown.

calculate the molar heat enthalpy for this reaction ?

[C-H = 411 ; H-Cl=428 ; Cl-Cl=240 ; C-Cl=327]

a)

-104 KJ

b)

+104 KJ

c)

+327 KJ

d)

-250 KJ

7.

The process of dissolution can be considered to involve three steps. Which of the following is not one of these steps?

a)

The separation of solvent–solute interactions

b)

The separation of solvent–solvent intermolecular attractions

c)

The formation of solute–solvent interactions

d)

The separation of solute–solute attractions

8.

What is the enthalpy change of dilution, Δ𝐻dil?

a)

71.2 KJ

b)

-13.2 KJ

c)

-71.2 KJ

d)

+ 13.2 KJ

9.

what do X and Y represent respectively?

a)

ΔH melting & Δ H evaporation

b)

ΔH Fusion & Δ H evaporation

c)

ΔH condensation & Δ H evaporation

d)

ΔH Fusion & Δ H solution

10.

What standard enthalpy change can be defined as the enthalpy change when one mole of a substance transforms from a liquid state to a solid state under standard conditions?

a)

Standard enthalpy of fusion

b)

Standard enthalpy of vaporization

c)

Standard enthalpy of sublimation

d)

Standard enthalpy of solidification

e)

Standard enthalpy of condensation

11.

Which of the following values is equivalent to Δ𝐻3?

a)

−Δ𝐻1+Δ𝐻2+Δ𝐻4

b)

Δ𝐻1 - Δ𝐻2 - Δ𝐻4

c)

− Δ𝐻1- Δ𝐻2 - Δ𝐻4

d)

+ Δ𝐻1+Δ𝐻2+Δ𝐻4

12.

Considering the diagram, which of the following equations would Hess’s law predict to be true?

a)

Δ𝐻2=Δ𝐻3−Δ𝐻1

b)

Δ𝐻1=Δ𝐻2+Δ𝐻3

c)

Δ𝐻1=Δ𝐻2-Δ𝐻3

d)

Δ𝐻2=Δ𝐻3+Δ𝐻1

13.

The reaction represents ……. reaction

a)

Exothermic

b)

endothermic

c)

Neither exothermic nor endothermic

14.

A piece of copper of mass 400 g absorbed a quantity of heat of 9360 J & its temperature raised from 20˚C to 50˚C. What is the specific heat of copper?

a)

0.78 J/gC

b)

1.282 J/gC

c)

7.8 J/gC

d)

4.18 J/gC

15.

Determine the final temperature when a 25 g piece of iron at 85˚C is placed into 75 g of water at 20˚C. (given that: specific heat of iron is 0.45 & water equals 4.184 j/g.˚C)

a)

52.5 °C

b)

22.25 °C

c)

60.5 °C

d)

45.25 °C