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STRUCTURAL ISOMERISM

Total questions: 15

Worksheet time: 8mins

Name
Class
Date
1.

Which among the given molecules can exhibit tautomerism? (NEET-II 2016)

a)

III only

b)

Both I and III

c)

Both I and II

d)

Both II and III

2.

Which of the given compounds can exhibit tautomerism?(NEET 2015)

a)

II and III

b)

I, II and III

c)

I and II

d)

I and III

3.

The enolic form of ethyl acetoacetate as shown below has

a)

9 sigma bonds and 2 pi-bonds

b)

9 sigma bonds and 1 pi-bond

c)

18 sigma bonds and 2 pi-bonds

d)

16 sigma bonds and 1 pi-bond.

4.

Which one of the following pairs represents stereoisomerism? (NEET 2005)

a)

Structural isomerism and geometrical isomerism

b)

Optical isomerism and geometrical isomerism

c)

Chain isomerism and rotational isomerism

d)

Linkage isomerism and geometrical isomerism

5.

Tautomerism is exhibited by

a)

R3CNO2

b)

RCH2NO2

c)

(CH3)3CNO

d)

(CH3)2NH

6.

Isomers of a substance must have the same

a)

structural formula

b)

physical properties

c)

chemical properties

d)

molecular formula.

7.

Which of the following compounds will show metamerism?

a)

CH3 –O–C2 H5

b)

CH3 –O–CH3

c)

C2 H5 –CO– CH3

d)

C2 H5 –S–C2 H5

8.

The enolic form of acetone contains

a)

9 sigma bonds, 1 pi bond and 2 lone pair of electrons

b)

8 sigma bonds, 2 pi bonds and 2 lone pair of electrons

c)

10 sigma bonds, 1 pi bond and 1 lone pair of electrons

d)

9 sigma bonds, 2 pi bonds and 1 lone pair of electrons

9.

C6H5C ≡ N and C6H5N → C are which type of isomers?

a)

Tautomerism

b)

Position

c)

Functional

d)

Linkage

10.

An isomer of ethanol is

a)

Methanol

b)

Diethyl ether

c)

Acetone

d)

Dimethyl ether

11.

Maximum enol content is observed in

a)
b)
c)
d)
12.

Tautomerism is exhibited by

a)

1 and 2

b)

1, 3 and 4

c)

1, 2 and 4

d)

1, 2, 3 and 4

13.

Following types of compounds are studied under which type of isomerism?

a)

Chain isomerism

b)

Position isomerism

c)

Conformers

d)

Stereoisomerism

14.

In which of the following, functional group isomerism is not possible?

a)

Alcohols

b)

Aldehydes

c)

Alkyl halides

d)

Cyanides

15.

(A) : Enol form of cyclohexane-1,3,5 trione is more stable

than its keto form.

(R) : Enol form contains α-hydrogen atoms

a)

if A and R both are correct and R is the correct explanation of A;

b)

if A and R both are correct but R is not the correct explanation of A

c)

A is true but R is false

d)

A is false but R is true