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Chemistry STPM : Semester 2

Total questions: 15

Worksheet time: 10mins

Name
Class
Date
1.

Consider the following bond enthalpies.


Bond ------ Enthalpy (kJ mol-1)

Br – Br ---------- 194

H – Br ---------- 362

C – H ----------- 414

C - Br ----------- 285

What is the enthalpy change for the reaction in diagram?

a)

-1255 kJmol-1

b)

-39 kJmol-1

c)

+39 kJmol-1

d)

+1255 kJmol-1

2.

The following data are needed for this question.


∆HfƟ (CO(g)) = –111 kJ mol-1

∆HfƟ (CO­2(g)) = –394 kJ mol-1

∆HfƟ (Fe2O3(s)) = –822 kJ mol-1


Carbon monoxide reacts with iron(III) oxide.

3CO(g) + Fe2O3(s) → 3CO2(g) + 2Fe(s)

What is the enthalpy change when 55.8 g of iron are produced by this reaction?

a)

–27.0 kJ

b)

–13.5 kJ

c)

+13.5 kJ

d)

+27.0 kJ

3.

Copper reacts with dilute nitric acid to produce nitrogen dioxide gas. The balanced ionic equation is given.

Cu + 2H+ + 2HNO3 --> Cu2+ + 2NO2 + 2H2O

Which of the following is correct?

a)

A

b)

B

c)

C

d)

D

4.

Which of the following will occur in the cell shown ?

a)

The blue colour in Y will become less intense.

b)

The mass of the electrode in Y will decrease.

c)

The concentration of the solution in X will increase.

d)

Electrons will flow from X to Y through the salt bridge.

5.

The table shows the successive ionisation energies for an element X.

What could be the formula of the fluoride of X ?

a)

XF

b)

XF2

c)

XF3

d)

XF4

6.

X, Y and Z are elements in Period 3 of the Periodic Table.

A mixture containing the oxides of X, Y and Z was dissolved in excess dilute sulfuric acid and filtered. The oxide of Z was collected as a residue. When excess dilute sodium hydroxide was added to the filtrate, only a white precipitate of the hydroxide of Y was formed.

What are the possible identities of X, Y and Z?

a)

A

b)

B

c)

C

d)

D

7.

Samples of magnesium carbonate, MgCO3, are placed in crucibles R and S.

The sample in crucible R is heated until there is no further loss in mass, and then allowed to cool.

The sample in crucible S is left unheated.

Dilute hydrochloric acid is then added to both crucibles.

On adding the dilute hydrochloric acid, which observations are correct?

a)

A

b)

B

c)

C

d)

D

8.

In the reaction shown, M represents a Group 2 element.

MO2 → MO + ½ O2

Which statement about this reaction is correct?

a)

It is a redox reaction.

b)

The anion in MO2 contains 8 electrons.

c)

The lattice energy of MO2 is greater in magnitude than the lattice energy of MO.

d)
9.

In the preparation of silicon, silicon dioxide is heated with magnesium.

SiO2 + 2Mg --> 2MgO + Si

The product mixture contains MgO and Si only. To separate the silicon from the product mixture, students proposed the following two possible methods :

1. Shake the mixture with aqueous hydrochloric acid and filter.

2. Heat the mixture gently and collect the evaporated silicon.

Which methods would work?

a)

1 and 2

b)

1 only

c)

2 only

d)

neither 1 or 2

10.

Germanium is between silicon and tin in Group 14. Which one of the following statements about germanium chemistry is least likely to be true?

a)

The element has a diamond type structure

b)

The oxide will dissolve in aqueous sodium hydroxide

c)

The element is a better electrical conductor than tin

d)

Germanium-oxygen covalent bonds will be weaker than silicon-oxygen bonds.

11.

A type of silicate has the structure like shown in the diagram.

Which of the following is true about the above structure ?

I It can be found in amphiboles

II Its anion is Si 4O116-

III the mineral with the above structure is asbestos

a)

I only

b)

I and II only

c)

II and III only

d)

I , II and III

12.

For elements in Group 17 of the Periodic Table, which of the following statements is true as the group is descended?

a)

The boiling point decreases.

b)

The covalent radius decreases.

c)

The first ionisation energy increases.

d)

The strength of the van der Waals’ forces increases.

13.

The highest oxidation state of chlorine is present in

a)

HClO

b)

HClO2

c)

HClO3

d)

HClO4

14.

When concentrated sulfuric acid reacts with sodium iodide the products include sulfur, iodine, hydrogen sulfide and sulfur dioxide.

Which statement is correct?

a)

Hydrogen sulfide is the product of a reduction reaction.

b)

Iodide ions are stronger oxidising agents than sulfate ions

c)

Sulfur atoms from the sulfuric acid are both oxidised and reduced.

d)

Sulfur atoms from the sulfuric acid are oxidised to make sulfur dioxide

15.

The electron configuration of chromium in CrO42- ion is

a)

1s2 2s2 2p6 3s2 3p6

b)

1s2 2s2 2p6 3s2 3p63d5

c)

1s2 2s2 2p6 3s2 3p63d5 4s1

d)

1s2 2s2 2p6 3s2 3p6 3d4 4s2