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Chem-is-try Challenge 27

Total questions: 7

Worksheet time: 14mins

Name
Class
Date
1.

A Born-Haber cycle for calcium oxide is shown in the diagram above.

Which enthalpy changes have negative values?

a)

p, t, w

b)

p, v, w

c)

q, s, u

d)

t, v, w

2.

The thermochemical equation for the neutralisationS reaction of sulphuric acid by aqueous solution of potassium hydroxide is given below

2KOH(aq) + H2SO4(aq) → K2SO4(aq) + 2H2O(l)

ΔH0= -114 kJ

What is the standard enthalpy of neutralisation, in kJ mol-1, for the reaction between nitric acid with an aqueous solution of sodium hydroxide?

a)

-28.5

b)

-57

c)

-114

d)

-228

3.

Which compound has the lowest lattice energy?

a)

CaCl2

b)

CsCl

c)

K2O

d)

MgCl2

4.

The half-cell equation and the standard reduciton potential for X and Y are shown below

X2+(aq) + 2e- ↔ X(s) +0.34V

Y+(aq) + e- ↔ Y(s) +0.80V

What is the e.m.f. of the cell constructed from the two half cells?

a)

-1.14V

b)

-0.46V

c)

+0.46V

d)

+1.26V

5.

The Nernst equation is written as

Ecell = E0cell - 0.059/n logQ

For the reaction Mg(s) + 2H+(aq) → Mg2+(aq) + H2(g), Q may be expressed as

a)

[Mg2+][Mg][H+]2\frac{\left[Mg^{2+}\right]}{\left[Mg\right]\left[H^+\right]^2}

b)

[Mg2+]pH2[Mg][H+]2\frac{\left[Mg^{2+}\right]p_{H_2}}{\left[Mg\right]\left[H^+\right]^2}

c)

[Mg2+]pH2[H+]2\frac{\left[Mg^{2+}\right]p_{H_2}}{\left[H^+\right]^2}

d)

[H+]2[Mg2+]PH2\frac{\left[H^+\right]^2}{\left[Mg^{2+}\right]P_{H_2}}

6.

An electrochemical cell is shown in the diagram above.

Standard reduction potential for X is -0.76V. Which statement is NOT true of the above cell?

a)

Hydrogen is a weaker reducing agent than X

b)

The cell diagram is Pt(s), H2(g)∣H+(aq)∥Xn+(aq)∣X(s)

c)

The voltmeter reading at standard condition is 0.76V

d)

The equation for the overall cell reaction is 2X(s) + 2nH+(aq) → 2Xn+(aq) + nH2(g)

7.

Which statement explains why graphite powder is spread onto plastic material first in plastic electroplating process?

a)

Graphite is an electric conductor

b)

Plastic becomes more resistant to heat

c)

Plastic electroplating process is accelerated

d)

Graphite can form chemical bond with plastic