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Revision Chapter 2: Atomic Structure

Total questions: 22

Worksheet time: 6hrs 30mins

Name
Class
Date
1.

In a line spectrum of emission of hydrogen atom, how many lines can be observed if the electrons transit within n=4 and n=1

a)

3

b)

4

c)

5

d)

6

2.

Line corresponding to the shortest wavelength is obtained in a hydrogen spectrum when the electron drops from

a)

n=2 to n=1

b)

n=3 to n=1

c)

n=4 to n=2

d)

n=4 to n=1

3.

Choose the transition of electrons involving the greatest energy change.

a)

n=4 to n=3

b)

n=3 to n=1

c)

n=4 to n=2

d)

n=4 to n=1

4.

The electronic configuration with the lowest energy for 7 electrons in a 3d subshell is obtained based on

a)

Hund's rule

b)

The Aufbau principle

c)

The Pauli Exclusion Principle

d)

The Heisenberg's uncertainty principle

5.

What is the wavelength, λ of the fourth line in the Balmer series?

a)

410 nm

b)

432 nm

c)

486 nm

d)

654 nm

6.

Calculate the energy required to excite an electron from n=2 to n=4

a)

4.09 x10-19 J

b)

5.45 x10-19 J

c)

2.05 x106 J

d)

2.74 x106 J

7.

Pick the transition resulting the shortest wavelength

a)

P

b)

Q

c)

R

d)

S

8.

The diagram shows lines of emission spectrum in Balmer Series. Select the transition of electron that gives rise to the line L.

a)

n=1 to n=5

b)

n=3 to n=2

c)

n=4 to n=2

d)

n=5 to n=2

9.

An atom with principal quantum number, n=3 has a total number of orbitals of

a)

13

b)

14

c)

16

d)

18

10.

What is the frequency, in s-1 of a radiation with energy of 3.37 x 10-19 J per photon?

a)

5.08 x 10-54 s-1

b)

5.08 x 1014 s-1

c)

5.08 x 10-15 s-1

d)

5.08 x 1015 s-1

11.

What is the energy, in J, of one mole of photons emitted with a frequency of 6.336 x 1015 Hz?

a)

4.20 x 10-18 J

b)

3.96 x 106 J

c)

2.53 x 106 J

d)

3.88 x 1014 J

12.

A possible set of quantum numbers for an electron in the 3d-orbital is

a)

(n.l,m,s) = (3,1,+1,-1/2)

b)

(n.l,m,s) = (3,2,0,-1/2)

c)

(n.l,m,s) = (3,1,+3,+1/2)

d)

(n.l,m,s) = (3,3,+2,-1/2)

13.

Which of the following electronic configuration is for 7N3+ ?

a)

1s2 2s2

b)

1s2 2s2 2p3

c)

1s2 2s2 2p6

d)

1s2 2s2 2p6 3s1

14.

The electronic configuration of oxygen atom in the ground state is represented by

a)
b)
c)
d)
15.

What is the electronic configuration for Ni2+?

a)

[Ar] 3d6

b)

[Ar] 3d8

c)

[Ar] 3d10

d)

[Ar] 3d8 4s2

16.

The maximum number of electrons occupying atomic orbitals of shell M (n=3) is

a)

8

b)

10

c)

18

d)

32

17.

Orbital with quantum number, n=3, l =2 and m=+2 is

a)

2p

b)

3s

c)

3p

d)

3d

18.

The electronic configuration of copper atom is 1s2 2s2 2p6 3s2 3p6 3d10 4s1.


Determine the number of electrons in the copper atom in ground state with the azimuthal quantum number l=0.

a)

7

b)

8

c)

10

d)

12

19.

For 18Ar, calculate the total number of electrons with magnetic quantum number, m=0.

a)

8

b)

10

c)

12

d)

16

20.

Which of the following represent an element that forms ion with a charge of -2?

a)

1s2 2s2 2p6 3s2

b)

1s2 2s2 2p6 3s2 3p2

c)

1s2 2s2 2p6 3s2 3p4

d)

1s2 2s2 2p6 3s2 3p5

21.

After filling up the 3p orbital, which orbital must electrons next occupy?

a)

3d

b)

4s

c)

4p

d)

3s

22.

Which of the following defines the Pauli exclusion principle?

a)

When electrons are filled into orbitals with equivalent energy, the electrons occupy each orbital singly before they occupy the orbitals in pairs/

b)

An orbital can hold maximum of 2 electrons with different quantum numbers

c)

Electrons occupy the orbital with the lowest energy first before they occupy orbitals with higher energy

d)

Half-filled orbitals contribute to the stability of an atom