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Ch 17 Reactions of Alcohols

Total questions: 19

Worksheet time: 11mins

Name
Class
Date
1.

Halogenoalkanes can undergo an elimination reaction with sodium hydroxide in ethanol. A similar dehydration/elimination reaction takes place with alcohols. What reaction conditions are required?

a)

Al2O3 and heat

b)

NaOH in ethanol

c)

acidified K2Cr2O7

d)

two of these

2.

When treated with sulfuric acid @ 170 C, which of these molecules will produce the greatest number of structural and/or geometric isomers?

a)

ethanol

b)

2-butanol

c)

3-pentanol

d)

1-propanol

3.

Which of the following molecules will be oxidized into propanone with acidified potassium dichromate?

a)

1-propanol

b)

2-propanol

c)

1-butanol

d)

2-methyl-2-propanol

4.

Which pair of molecules will BOTH produce carboxylic acids when fully oxidized by acidified potassium dichromate?

a)

1-propanol & 2-propanol

b)

ethanol & 2-propanol

c)

2-propanol & 1-butanol

d)

1-propanol & 1-butanol

5.

What is the proper observation to record when this molecule is treated with acidified potassium dichromate?

a)

solution turns green

b)

solution remains orange

c)

solution remains green

d)

bubbles, orange ppt.

6.

In addition to potassium dichromate, which of the following reagents/reaction conditions can ALSO be used to OXIDIZE alcohols?

a)

aluminum oxide in sulfuric acid

b)

phosphoric acid, 330 C and 6 MPA

c)

acidified potassium permanganate

d)

NaOH in ethanol

7.

Which of the following, when added to 2-methylbutanoic acid, would produce bubbles?

a)

Mg and NaOH

b)

NaOH and Na2CO3

c)

Mg only

d)

Mg & Na2CO3

8.

When halogenation takes place 'in situ', which of the following is/are added to the reaction flask, in addition to the alcohol?

a)

a hydrogen halide

b)

sulfuric acid and an alkali metal halide, such as NaBr

c)

an alkali metal halide such as NaBr

d)

sulfuric acid, NaCl AND HBr

9.

Which of the following reagents is used to test for the presence of a hydroxy group (an OH) via a nucleophilic substitution reaction?

a)

SOCl2

b)

PCl5

c)

PBr3

d)

NaCl & sulfuric acid

10.

Which of the following molecules would have the least vigorous reaction with sodium, Na(s)?

a)

ethanol

b)

1-propanol

c)

water

d)

2-butanol

11.

"squeaky pop" is the observation confirming the presence of which gas?

a)

O2

b)

H2

c)

CO2

d)

H2O

12.

What is esterification?

a)

saying 'its terrific!' to someone really fast

b)

the reaction that occurs between an alcohol and a carboxylic acid to form an ester

c)

the reaction that occurs between an alcohol and a ester to form a carboxylic acid

d)

the reaction that occurs when an ester breaks down into an alcohol and a carboxylic acid

13.

Which of the following will react in the presence of sulfuric acid to produce propyl butanoate?

a)

1-propanol and butanoic acid

b)

2-propanol and sodium butanoate

c)

1-propanol and butanone

d)

2-propanol and butanoic acid

14.

Which of the following will react to form hydrogen gas and an alkoxide salt?

a)

ethanol and sodium

b)

1-propanol and sodium butanoate

c)

sodium hydroxide and propyl ethanoate

d)

HCl, ethanol and methanoic acid

15.

Which of the following will react with sulfuric acid to produce 1-butanol and ethanoic acid?

a)

butyl ethanoate

b)

ethyl butanoate

c)

none of these

d)

either of these

16.

What are the products of the hydrolysis of ethyl propanoate with potassium hydroxide?

a)

ethanol and potassium propanoate

b)

1-propanol and potassium ethanoate

c)

ethanol and propanoic acid

d)

1-propanol and ethanoic acid

17.

Which of the following molecules can be reduced using LiAlH4?

a)

primary & secondary alcohols ONLY

b)

carboxylic acids & ketones

c)

carboxylic acids, ketones & aldehydes

d)

ketones and primary alcohols ONLY

18.

A clear, colorless liquid produces bubbles upon the addition of Mg and potassium carbonate, respectively, but no observable reaction occurs upon the addition of sodium hydroxide. What is the likely identity of the solution?

a)

1-propanol

b)

propyl ethanoate

c)

propanoic acid

d)

propanone

19.

Acidified potassium dichromate was added to two different test tubes containing two different solutions. Which of the following is/are true about the identity of the solutions (before)?

a)

Left: 1-butanol Right: 2-butanol

b)

Left: 2-butanol Right: 1-butanol

c)

Left: 2-methyl-2-butanol

Right: 1-butanol

d)

Left: 2-methyl-2-butanol

Right: 3-ethyl-3-pentanol