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Worksheets

Kinetics Calculations

Total questions: 20

Worksheet time: 1hrs 10mins

Name
Class
Date
1.

What is the rate of the following reaction?

C2H4(g)+O3(g)⟷ C2H4O(g)+O2(g)C_2H_{4\left(g\right)}+O_{3\left(g\right)}\longleftrightarrow\ C_2H_4O_{\left(g\right)}+O_{2\left(g\right)}  

a)

−Δ[O2]Δt-\frac{\Delta\left[O_2\right]}{\Delta t}  

b)

−Δ[C2H4O]Δt-\frac{\Delta\left[C_2H_{\text{4}}O\right]}{\Delta t}  

c)

−Δ[O3]Δt-\frac{\Delta\left[O_3\right]}{\Delta t}  

d)

−Δ[C2H4]Δt-\frac{\Delta\left[C_2H_4\right]}{\Delta t}  

2.

Calculate the average rate based on the table given and the equation below:

C2H4+O3→C2H4O+O2C_2H_4+O_3\rightarrow C_2H_4O+O_2  

a)

3.50×10−7 mol L−1⋅s−13.50\times10^{-7}\ mol\ L^{-1}\cdot s^{-1}  

b)

7.1×10−77.1\times10^{-7}  mol/L/s

c)

−3.50×10−7 mol L⋅s-3.50\times10^{-7}\ mol\ L\cdot s  

d)

−7.1×10−7 -7.1\times10^{-7\ }  mol/L

3.

What is the reaction order of all the reactants? What is the overall reaction order? Use the following equation and rate law: H2O2(aq)+3I−(aq)+2H(aq)+ → I3(aq)−+2H2O(l);rate=k[H2O2][I−]H_2O_{2(aq)}+3I^-(aq)+2H_{(aq)}^+\ \rightarrow\ I_{3(aq)}^-+2H_2O_{(l)};rate=k[H_2O_2][I^-]  

a)

The reaction is zero-order in H2O2H_2O_2  , 1st order in I−I^-    and zero-order in H+H^+  ,  and 6th order overall.

b)

The reaction is 1st order in H2O2H_2O_2  , 1st order in I−I^-    and zero-order in H+H^+  ,  and 2nd order overall.

c)

The reaction is 1st order in H2O2H_2O_2  , 3rd order in I−I^-    and 2nd order in H+H^+  ,  and 6th order overall.

d)

The reaction is 1st order in H2O2H_2O_2  , 3rd order in I−I^-    and 2nd order in H+H^+  ,  and 2nd order overall.

4.
a)

A

b)

B

c)

C

d)

D

5.

Find m.

a)

m = 4

b)

m = 2

c)

m = 1

d)

m = 0

6.

Find n.

a)

n = 4

b)

n = 2

c)

n = 1

d)

n = 0

7.

Find p.

a)

p = 4

b)

p = 2

c)

p = 1

d)

p = 0

8.

What is the overall reaction order?

a)

1

b)

2

c)

3

d)

4

9.

 At 1000 degrees C, cyclobutane ( C4H8C_4H_8  ) decomposes in a first-order reaction with the very high rate constant of 87 s−187\ s^{-1}  to yield two molecules of ethylene ( C2H4C_2H_4  ). If the initial [ C4H8C_4H_8 ] is 2.00 M, what is the concentration after 0.010 s of reaction?

a)

0.1 M

b)

1.13 M

c)

83 M

d)

0.83 M

10.

What is the answer for part a?

a)

0.46 s0.46\ s  

b)

0.075 s0.075\ s  

c)

0.75 s0.75\ s  

d)

4.6 s4.6\ s  

11.

What is the answer for part b?

a)

0.375 s0.375\ s  

b)

0.015 s0.015\ s  

c)

0.15 s0.15\ s  

d)

0.0375 s0.0375\ s  

12.

This is a ____ -order reaction.

a)

first

b)

second

c)

third

d)

zero

13.

This is a ____ -order reaction.

a)

first

b)

second

c)

third

d)

zero

14.

This is a ____ -order reaction.

a)

first

b)

second

c)

third

d)

zero

15.
a)

176 mol/kJ

b)

1.76 kJ/mol

c)

176 kJ/mol

d)

1.76 mol/kJ

16.

A catalysts that exists in solution with the reaction mixture is _______

a)

solid

b)

heterogenous

c)

liquid

d)

homogenous

17.

A catalyst that is in a different phase from the reaction mixture is __________

a)

solid

b)

heterogenous

c)

liquid

d)

homogenous

18.

this is a _______-order reaction.

a)

zero

b)

first

c)

second

d)

third

19.

this is a _______-order reaction.

a)

zero

b)

first

c)

second

d)

third

20.

this is a _______-order reaction.

a)

zero

b)

first

c)

second

d)

third