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Chem Exam 2

Total questions: 21

Worksheet time: 5hrs 15mins

Name
Class
Date
1.

Considering the rate law: rate = k[CO2][CH4]3

The reaction is ______ order with respect to CO2

a)

1st

b)

2nd

c)

3rd

d)

4th

2.

Considering the rate law: rate = k[CO2][CH4]3

The reaction is ______ order with respect to CH4.

a)

1st

b)

2nd

c)

3rd

d)

4th

3.

Considering the rate law: rate = k[CO2][CH4]3

The reaction is ____ order overall.

a)

1st

b)

2nd

c)

3rd

d)

4th

4.

Select all of the true statements about the half-life of a reaction.

a)

It is calculated in different ways for different orders of reaction

b)

It is the time required for the concentration of a reactant to decrease to half of its initial value

c)

It is always independent of initial reactant concentration

d)

It is the time required for the concentration of a reactant to decrease to zero

5.

Consider the reaction mechanism:

Step 1: NO(g) +Cl2(g) --> NOCl2(g)               fast

Step 2: NOCl2(g) + NO(g) --> 2NOCl(g)       slow

______ is an intermediate.

a)

NOCl2

b)

Cl2

c)

NO

d)

NOCl

6.

Consider the reaction mechanism:

Step 1: NO(g) +Cl2(g) --> NOCl2(g)               fast

Step 2: NOCl2(g) + NO(g) --> 2NOCl(g)       slow

This reaction has _____ elementary steps.

a)

0

b)

1

c)

2

d)

3

7.

Consider the reaction mechanism:

Step 1: NO(g) +Cl2(g) --> NOCl2(g)               fast

Step 2: NOCl2(g) + NO(g) --> 2NOCl(g)       slow

Step _____ is the rate determining step.

a)

0

b)

1

c)

2

d)

3

8.

For the following reaction, select the correct equilibrium constant expression.

2KCl (aq) + MgBr2(aq) --> 2KBr(aq) + MgCl2(aq)

a)

A

b)

B

c)

C

d)

D

9.

Considering the following reaction, predict the direction in which the reaction will shift its equilibrium under the following stresses.

N2(g) + 3H2(g) --> 2NH3(g)

If you increase the concentration of N2, the reaction will shift towards the _______.

a)

Products

b)

Reactants

c)

Neither

10.

Considering the following reaction, predict the direction in which the reaction will shift its equilibrium under the following stresses.

N2(g) + 3H2(g) --> 2NH3(g)

If you increase the concentration of NH3, the reaction will shift towards the _______.

a)

Products

b)

Reactants

c)

Neither

11.

Considering the following reaction, predict the direction in which the reaction will shift its equilibrium under the following stresses.

N2(g) + 3H2(g) --> 2NH3(g)

If you decrease the concentration of H2 and N2, the reaction will shift towards the       ________.

a)

Products

b)

Reactants

c)

Neither

12.

Considering the following reaction, predict the direction in which the reaction will shift its equilibrium under the following stresses.

N2(g) + 3H2(g) --> 2NH3(g)

If you increase the volume of the reaction mixture at a constant temperature, the reaction will shift towards the       ________.

a)

Products

b)

Reactants

c)

Neither

13.

The following reaction is an example of heterogeneous equilibrium:

MgSO4(s) MgO(aq) + SO3(aq)

a)

True

b)

False

14.

Match the correct acid definition to the Theory: Arrhenius

a)

substance dissolved in water that increases hydroxide ion concentration

b)

proton acceptor

c)

electron pair donor

15.

Match the correct acid definition to the Theory: Bronsted Lowry

a)

substance dissolved in water that increases hydroxide ion concentration

b)

proton acceptor

c)

electron pair donor

16.

Match the correct acid definition to the Theory: Lewis

a)

substance dissolved in water that increases hydroxide ion concentration

b)

proton acceptor

c)

electron pair donor

17.

Select the indicated species in each reaction:

a. HCl(aq) + H2O(aq) --> Cl-(aq) + H3O+(l) the conjugate acid is _______

a)

H2O

b)

Cl-

c)

H3O+

d)

HCl

18.

Select the indicated species in each reaction:

b. HBr(aq) + H2O(l) --> H3O+(l) + Br-(aq) the conjugate base is _______

a)

HBr

b)

H2O

c)

H3O+

d)

Br-

19.

Select the indicated species in each reaction:

c. HCl(aq) + NH3(aq) --> NH4Cl(aq) the base is _______

a)

HCl

b)

NH3

c)

NH4Cl

20.

Nitrous acid has a Ka = 7.2x10-4 and a Kb = 1.4x10-11. Phenol has a Ka = 1.0x10-10 and a Kb = 1.x10-4.       

________ is the strongest acid.  

a)

Phenol

b)

Nitrous acid

21.

Nitrous acid has a Ka = 7.2x10-4 and a Kb = 1.4x10-11. Phenol has a Ka = 1.0x10-10 and a Kb = 1.x10-4.       

________ has the strongest conjugate base.

a)

Phenol

b)

Nitrous acid