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Topic 14 Bonding

Total questions: 27

Worksheet time: 2hrs 13mins

Name
Class
Date
1.

Which contain delocalised electrons?

I.   C6H5OH

II.  CH3COOI

II. CO32−

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

2.

What is the electron domain geometry of Si in SiO2?

a)

bent

b)

linear

c)

square planar

d)

tetrahedral

3.

Which combination correctly describes the geometry of BrF4-?

a)

A

b)

B

c)

C

d)

D

4.

Which atom does not obey the octet rule?

a)

C in CO2

b)

F in BF3

c)

O in H2O

d)

S in SF6

5.

Which species has delocalized electrons?

a)

OH

b)

H2CO

c)

CO2

d)

CO32−

6.

Which species has a square planar molecular geometry?

a)

SF4

b)

XeF4

c)

CF4

d)

PF4+

7.

How many sigma (σ) and pi (π) bonds are present in hydrogen cyanide, HCN?

a)

A

b)

B

c)

C

d)

D

8.

What is the number of sigma (σ) and pi (π) bonds in the molecule (NC)2C=C(CN)2?

a)

A

b)

B

c)

C

d)

D

9.

Which can be represented with only one Lewis structure?

a)

CH2O

b)

C6H6

c)

O3

d)

NO3

10.

Which molecule has an expanded octet?

a)

CO

b)

CO2

c)

SF2

d)

SF4

11.

Which overlap of atomic orbitals leads to the formation of only a sigma (σ) bond?

       I.     s − p

       II.     p − p

       III.     s − s

a)

 I and II only     

b)

I and III only

c)

II and III only

d)

I, II and III

12.

How many sigma (σ) and pi (π) bonds are present in this molecule?

a)

12 σ; 6 π

b)

14 σ; 5 π

c)

16 σ; 6 π

d)

17σ; 5 π

13.

Which combination describes the PH4+ ion?

a)

A

b)

B

c)

C

d)

D

14.

Which combination describes the bonding and structure in benzoic acid, C6H5COOH?

a)

3 electron domains;

6 π electrons;

6 σ bonds

b)

3 electron domains;

8 π electrons;

15 σ bonds

c)

4 electron domains;

6 π electrons;

6 σ bonds

d)

4 electron domains;

8 π electrons;

10 σ bonds

15.

Which species have resonance structures?

I.     Ozone, O3

II.     Carbon dioxide, CO2

III.     Benzene, C6H6

a)

I and II only

b)

I and III only

c)

II and III only

d)

I , II and III

16.

Which does not show resonance?

a)

PO43–

b)

C6H6

c)

C6H12

d)

O3

17.

Which statement is correct?

a)

Sigma bonds are formed only by the combination of s atomic orbitals.

b)

Pi bonds can be formed in the absence of sigma bonds.

c)

Pi bonds are formed parallel to the axis between atoms.

d)

Pi bonds are formed only by the combination of hybrid orbitals.

18.

Which species breaks the octet rule?

a)

PCl3

b)

BF4

c)

SCl4

d)

NH4+

19.

Which species has bond angles of 90°?

a)

AlCl4-

b)

Cl4-

c)

NH4+

d)

SiCl4

20.

In which group do both compounds contain delocalized electrons? 

a)

C6H10, C5H10

b)

Na2CO3, NaOH

c)

NaHCO3, C6H6

d)

NaHCO3, C6H12

21.

What is the hybridization of the numbered atoms in ethanoic acid?

a)

Atom 1: sp3

Atom 2: sp

Atom 3: sp2

b)

Atom 1: sp3

Atom 2: sp2

Atom 3: sp

c)

Atom 1: sp2

Atom 2: sp3

Atom 3: sp2

d)

Atom 1: sp3

Atom 2: sp2

Atom 3: sp3

22.

In which series are all carbon atoms sp2 hybridized?

a)

C2H2; H2CO; HCOOH

b)

C2H4; H2CO; HCOOH

c)

C2H2; CO; HCN

d)

C2H6; CH3OH; CH3OCH3

23.

Which atom is sp2 hybridized?

a)

C in H2CO

b)

C in CO2

c)

N in CH3NH2

d)

O in H2O

24.

How many carbon atoms are sp3, sp2 and sp hybridized in the molecule?

a)

3 sp3

1 sp2

2 sp

b)

2 sp3

1 sp2

3 sp

c)

3 sp3

2 sp2

1 sp

d)

3 sp3

2 sp2

2 sp

25.

What is the hybridization of carbon and oxygen in methanol?

a)

C is sp2

O is sp2

b)

C is sp2

O is sp

c)

C is sp

O is sp2

d)

C is sp3

O is sp3

26.

What is the hybridization of the circled carbon, oxygen and nitrogen atoms?

a)

C: sp3 & tetrahedral

O: sp2 & trigonal planar

N: sp2 & trigonal planar

b)

C: sp2 & trigonal planar

O: sp & linear

N: sp3 & tetrahedral

c)

C: sp3 & tetrahedral

O: sp & linear

N: sp2 & trigonal planar

d)

C: sp3 & trigonal pyramidal

O: sp2 & trigonal planar

N: sp3 & trigonal pyramidal

27.

Which of the following is correct?

a)

A

b)

B

c)

C

d)

D