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Equilibrium and K

Total questions: 15

Worksheet time: 1hrs 15mins

Name
Class
Date
1.

Which is the correct equilibrium constant expression for the following reaction?

Fe2O3(s) + H2(g) —> Fe(s) + H2O(g)

a)

K = [H2O]3 / [H2]3

b)

K = [Fe2O3] [H2]3 / [Fe]2[H2O]3

c)

K = [Fe]2[H2O]3 / [Fe2O3] [H2]3

d)

K= [Fe] [H2O] / [Fe2O3] [H2]

e)

K = [H2] / [H2O]

2.

The equilibrium constant expression for the reaction BrF5(g) —> Br2(g) + F2(g) is


a)

Kc = [Br2] [F2] / [BrF5]

b)

Kc = [BrF5]2 / [Br2][F2]5

c)

Kc = [Br2] [F2]5 / [BrF5]2

d)

Kc = 2[BrF5]2 / ([Br2] × 5[F2]5)

e)

Kc = [Br2] [F2]2 / [BrF5]5

3.

The equilibrium between carbon dioxide gas and carbonic acid is very important in biology and environmental science. CO2(g) + H2O(l) —> H2CO3(aq)

Which one of the following is the correct equilibrium constant expression (Kc) for this reaction?

a)

Kc= 1/ [H2CO3]

b)

Kc= [CO2]/ [H2CO3]

c)

Kc= [H2CO3] / [CO2]

d)

Kc= [CO2] [H2O] / [H2CO3]

e)

Kc= [H2CO3] / [CO2] [H2O]

4.

Calculate Kc for the reaction HI(g) —> H2(g) + I2(g) given that the concentrations of each species at equilibrium are as follows: [HI] = 0.85 mol/L, [I2] = 0.60 mol/L, [H2] = 0.27mol/L.

a)

0.19

b)

0.22

c)

4.5

d)

5.25

e)

160

5.

A chemical reaction in which products can react to re-form reactants is known as a(n)

a)

reforming reaction

b)

reversible reaction.

c)

buffered reaction

d)

stoichiometric reaction.

6.

For any reaction at chemical equilibrium, the concentrations of products and reactants

a)

are equal.

b)

change

c)

remain unchanged

d)

decrease

7.

A very high value for K indicates that

a)

reactants are favored.

b)

products are favored.

c)

equilibrium is reached slowly.

d)

equilibrium has been reached

8.

This symbol indicates that a reaction is _____

a)

reversible

b)

irreversible

9.

Around what time does the reaction reach equilibrium?

a)

25 min

b)

70 min

c)

45 min

d)

80 min

10.

Which of the two graphs reaches equilibrium?

a)

Neither

b)

The left

c)

Both

d)

The right

11.

What states of matter are omitted when writing Keq expressions?

a)

solids and liquids

b)

aqueous solutions and gas

c)

solids, liquids, aqueous solutions and gases

d)

aqueous solutions & liquids

12.

When Keq < 1,

a)

There are more products than reactants when the reaction reached equilibrium.

b)

There are more reactant than products when the reaction reached equilibrium.

c)

The amount of reactants is equal to the amount of products.

13.

What is the Keq expression for this reaction?

2 NO(g) + O2(g) ⇌ 2 NO2(g)

a)

Kc = [NO2]2 / [NO]2 [O2]

b)

Kc = [NO]2 [O2] / [NO2]2

c)

Kc = [NO]2 [O2] [NO2]2

d)

Kc = [NO2]2 / [NO]2 + [O2]

14.

The following reaction :

SO2 (g) + NO2 (g) ⇌ SO3 (g) + NO (g)

established equilibrium and was found to contain

0.40 M SO3 , 0.30 M NO,

0.15 M NO2 , and 0.20 M SO2.

Calculate the equilibrium constant for this reaction.

a)

4.0

b)

.42

c)

.25

d)

1.0

15.

Calculate [H2O] if Keq = 1.2,

[CO2] = 0.846M, and [CH4]= 0.0713M

4CuO(s) +CH4(g) ⇌ CO2(g)+4Cu(s) +2H2O(g)

a)

0.101 M

b)

0.318 M

c)

0.0102 M

d)

3.77 M