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Photochemistry

Total questions: 15

Worksheet time: 8mins

Name
Class
Date
1.

What is the primary requirement for a photochemical reaction?

a)

Light

b)

Heat

c)

Pressure

d)

Chemical compounds

2.

Photochemistry deals with the absorption of

a)

Radiation

b)

Light

c)

Light radiation

d)

Sound

3.

Emission of light stops immediately after removal of light source

a)

Phosphoresence

b)

Luminescence

c)

Fluorescence

d)

Chemiluminescence

4.

Stark Einsteins law is applicable to

a)

Primary process

b)

secondary process

c)

chain termination process

d)

thermal reactions

5.

Quantum yield of a photo chemical reaction is always one.

a)

Agree

b)

Disagree

c)

May be

6.

Which of the following is a non-radiative transition between two electronic states of the same spin multiplicity.

a)

Internal conversion

b)

Inter-system crossing

c)

vibrational relaxation

d)

Phosphorescence

7.

Which of the following is a radiative transition between two electronic states of the same spin multiplicity and instantaneous process ?

a)

Phosphorescence

b)

fluorescence

c)

chemiluminescence

d)

photosensitization

8.

which one of the following is a non-radiative transition between two iso-energetic vibrational levels belonging to electronic states of different spin multiplicity

a)

Phosphorescence

b)

Inter-system crossing

c)

Fluorescence

d)

internal conversion

9.

____________ is a radiative transition between two electronic states of different spin multiplicity and occurs for a longer time even after the source is cut off.

a)

Fluorescence

b)

Phosphorescence

c)

Bio-luminescence

d)

Photo-sensitization

10.

(a)   is the number of molecules reacted divided by the number of photons absorbed by the system.

11.

What is the role of the uranyl ions added to oxalic acid solution in an chemical actinometer ?

a)

chain initiation

b)

photo sensitization

c)

catalyst

d)

reactant

12.

If two unpaired electrons are present, the spin state is called

a)

Singlet

b)

Triplet

c)

None of the above

13.

T1 to S0 transition is referred to as

a)

Phosphorescence

b)

Fluorescence

c)

Vibration cascade

14.

S1 to S0 radiative transition is called

a)

Fluorescence

b)

Phosphorescence

c)

Intersystem crossing

d)

Internal conversion

15.

Example for quantam yield less than one

a)

Formation of HCl

b)

Formation of SO2Cl2

c)

Formation of HBr

d)

All