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Worksheets

Alcohol and Phenol

Total questions: 20

Worksheet time: 41mins

Name
Class
Date
1.

Benzene diazonium chloride on reaction with phenol in weakly basic medium gives

a)

diphenyl ether

b)

p-hydroxyazobenzene

c)

Chlorobenzene

d)

Benzene

2.

Benzene diazonium chloride on reaction with phenol in weakly basic medium gives azo dye (p-hydroxy azobenzene) is called:

a)

Dows Reaction.

b)

Coupling Reaction

c)

Diazotisation reaction

d)

Sandmeyer Reaction

3.

Phenol reacts with bromine in CS2 at low temperature to give

a)

m-bromophenol

b)

o-and p-bromophenol

c)

p-bromophenol

d)

2,4,6-tribromophenol

4.

When phenol is treated with excess bromine water it gives

a)

m-bromophenol

b)

o- and p-bromophenol

c)

2,4-dibromophenol

d)

2,4,6-tribromophenol

5.

Dehydration of alcohol is an example of

a)

addition reaction

b)

elimination reaction

c)

substitution reaction

d)

redox reaction

6.

Phenol is less acidic than

a)

Methanol

b)

p-methoxyphenol

c)

p-nitrophenol

d)

Ethanol

7.

Monochlorination of toluene in sunlight followed by hydrolysis with aq. NaOH yields__________

a)

o-Cresol

b)

p-Cresol

c)

2, 4-Dihydroxytoluene

d)

Benzyl alcohol

8.

The process of converting alkyl halides into alcohols involves_____________

a)

addition reaction

b)

substitution reaction

c)

dehydrohalogenation reaction

d)

rearrangement reaction

9.

Which of the following name reactions produces salicyldehyde?

a)

Kolbe's reaction

b)

Rosenmund reduction

c)

Williamson's synthesis

d)

Reimer Tiemann reaction

10.

Choose the correct order of acidic strength.

a)

o-nitrophenol < o-cresol < phenol

b)

o-cresol < o-nitrophenol< phenol

c)

o-cresol < phenol < o-nitrophenol

d)

o-nitrophenol< phenolo < cresol

11.

The order of ease of dehydration of primary,secondary and tertiary alcohols is_______________

a)

30 < 20 < 10

b)

20 < 10 < 30

c)

30 > 20 > 10

d)

20 < 30 < 10

12.

Which of the following set of reactants is appropriate for the preparation of t-butyl ethyl ether?

a)

t-butyl chloride and Sodium ethoxide.

b)

Sodium tertiary butoxide and Ethyl chloride

c)

Ethyl chloride and Butyl alcohol

d)

Butyl chloride and Ethyl alcohol

13.

Phenols are more acidic than alcohols because

a)

Phenoxide ion is stablised by resonance

b)

Phenols are more soluble in polar solvents

c)

Phenoxide ion does not exhibit resonance

d)

Alcohols do not lose H atoms at all

14.

Why alcohols have higher boiling point than alkanes?

a)

Alcohols have Van der Waal's forces between the molecules

b)

Alcohols have intermolecular Hydrogern bonding

c)

Alcohols exist as dimers.

d)

Alcohols have intramolecular Hydrogen bonding.

15.

When phenol is treated with CHCl3 and NaOH the product formed is

a)

benzaldehyde

b)

salicylaldehyde

c)

benzoic acid

d)

salicylic acid

16.

Williamson's synthesis gives best results when sodium alkoxide reacts with___________

a)

Primary alkyl halides

b)

Tertiary alkyl halide

c)

Primary alcohol

d)

Tertiary alcohol

17.

Phenol is obtained by heating aqueous solution of which of the following?

a)

Aniline

b)

Benzene diazonium chloride

c)

Benzoic acid

d)

Benzyl alcohol

18.

Arrange the compounds in the decreasing order of acidic character

a)

A

b)

B

c)

C

d)

D

19.

Phenols produce 2,4,6-trinitro phenol using following reagents

a)

Dil HNO3

b)

Con HNO3

c)

Con HNO3 + Con H2SO4

d)

Con H2SO4

20.

The correct acidic strength of the following

a)

A

b)

B

c)

C

d)

D