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solutions+electro+kinetics

Total questions: 15

Worksheet time: 19mins

Name
Class
Date
1.

Which of the following behavior is true about the ideal binary liquid solution of liquids 'A' and 'B', If P0A<P0B?

a)

Plot of Ptotal vs XA is non-linear

b)

Plot of Ptotal vs XB is linear with +ve slope

c)

Plot of Ptotal vs XB is linear with slope = 0

d)

Plot of Ptotal vs XB is linear with -ve slope

2.

For an ideal solution containing two liquid components A and B, the Gibb's free energy of mixing is minimum, when the molar ratio of the liquids is

a)

1:1

b)

1:2

c)

1:1000

d)

1:10

3.

Dry air was passed successively through a solution of 5gm of a solute in 80 gm of water and then through pure water. The loss in mass of solution was 2.5gm and that of pure solvent was 0.04gm. What is the molecular mass of the solute?

a)

70.3

b)

71.43

c)

14.28

d)

14.06

4.

Due to osmosis, the volume of concentrated solution

a)

decreases slowly

b)

increases slowly

c)

increases rapidly

d)

decreases rapidly

5.

The amino acid of alanine has two isomers, such as α\alpha  - alanine and β\beta  - alanine. Whenequal masses of these two compounds are dissolved in equal masses of solvent, the solution of α\alpha  - alanine freezes at relatively lower temperature. Which isomer, has the larger equilibrium constant for ionization?

a)

α\alpha  - alanine

b)

β\beta  - alanine

c)

same for both

d)

unpredictable

6.

An aqueous solution of 10% NaCl ( consider ideal behaviour of the solution) is cooled. It will allow some.

a)

NaCl to crystallize

b)

water to freeze

c)

water to solidify along with some NaCl

d)

Precipitation of NaCl

7.

Four colorless salt solutions are placed are placed in each. Which solution finally turns blue?

a)

AgNO3

b)

Pb(NO3)2

c)

Zn(NO3)2

d)

Cd(NO3)2

8.

Use of lithium metal as an electrode in high energy density batteries is due to

a)

lithium is the lightest element

b)

lithium has the highest oxidation potential

c)

lithium is quite reactive

d)

lithium does not corrode easily

9.

Faraday's law of electrolysis fails when

a)

temperature increased

b)

inert electrodes are used

c)

a mixture of electrolytes are used

d)

none of these

10.

copper can be deposited from acidified copper sulphate and alkaline cuprous cyanide. If the same current is passed for a definite time.

a)

The amount of copper deposited from acidic copper sulphate will be higher

b)

the amount of copper deposited from alkaline cuprous cyanide will be higher

c)

the same amount of copper will be deposited

d)

copper will not deposit in either case

11.

Which of the following solution have highest resistance?

a)

1N - NaCl

b)

0.05N - NaCl

c)

2N - NaCl

d)

0.1N - NaCl

12.
a)
b)
c)
d)
13.

When molten ICl3 is electrolysed using platinum electrodes

a)

I2 is evolved at cathode and Cl2 at anode

b)

Cl2 is evolved at cathode and I2 at anode

c)

I2 is evolved at cathode and both I2 and Cl2 at anode

d)

electrolysis does not take place

14.

The hydrolysis of an ester was carried out seperartely with 0.05M HCl and 0.05M H2SO4. Which of the following is true for the first order rate constant of the reaction?

a)
b)
c)
d)
15.
a)

1

b)

2

c)

1.5

d)

0.5