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CHEM 122 Test 1 (Ch 12 and 13)

Total questions: 20

Worksheet time: 30mins

Name
Class
Date
1.

Which of the following quantities is generally not obtainable from a single heating or cooling curve of a substance, measured at atmospheric pressure

a)

melting point

b)

boiling point

c)

triple point

d)

heat of fusion

e)

heat of vaporization

2.

The phase diagram for xenon has a solid-liquid curve with a positive slope. Which of the following is true?

a)

solid xenon has a higher density than liquid xenon

b)

solid xenon has the same density as liquid xenon

c)

the phase diagram cannot be used to predict which phase of xenon is denser

d)

freezing xenon is an endothermic process

3.

Diethyl ether has a high vapor pressure which makes it a potential fire hazard in laboratories in which it is used. How much energy is released when 100.0 g is cooled from 53.0 oC to 10.0 oC

Boiling Point: 34.5 oC

Heat of vaporization: 351 J/g

specific heat capacity, (CH3)2O (l): 3.74 j/gK

specific heat capacity, (CH3)2O (g): 2.35 J/gK

a)

10.1 kJ

b)

13.1 kJ

c)

16.1 kJ

d)

45.2 kJ

e)

48.6 kJ

4.

Octane has a vapor pressure of 40 torr at 45.1 oC and 400 torr at 104.0 oC. What is its heat of vaporization?

a)

39.0 kJ/mol

b)

46.0 kJ/mol

c)

590 kJ/mol

d)

710 kJ/mol

5.

Neon atoms are attracted to each other by

a)

dipole-dipole forces

b)

dispersion forces

c)

hydrogen bonding

d)

covalent bonding

6.

In hydrogen iodide _____ are the most important intermolecular forces

a)

dipole dipole

b)

dispersion

c)

hydrogen bonding

d)

covalent bonds

7.

Which of the following atoms should have the greatest polarizability?

a)

F

b)

Br

c)

Po

d)

Pb

8.

The strongest intermolecular interactions between ethyl alcohol (CH3CH2OH) molecules arise from

a)

dipole-dipole

b)

dispersion

c)

hydrogen bonding

d)

ion-dipole

9.

Which of the following should have the highest boiling point?

a)

CF4

b)

CCl4

c)

CBr4

d)

CI4

10.

Which of the following should have the highest surface tension at a given temperature?

a)

CH4

b)

CF4

c)

CCl4

d)

CI4

11.

Which of the following terms refers to the resistance of liquid to flow?

a)

surface tension

b)

capillary action

c)

viscosity

d)

adhesion

12.

The energy gap between the conduction band and the valence band is large for

a)

conductors

b)

semiconductors

c)

insulators

d)

super conductors

13.

Select the type of interaction that best describes the attraction between Mg2+ ions and water molecules.

a)

dipole-dipole

b)

dipole-induced dipole

c)

ion-dipole

d)

ion-induced dipole

14.

Soda drinks bubble when the bottle is opened because

a)

the temperature of the soda increases

b)

exposure to atmospheric pressure squeezes the carbon dioxide from solution

c)

the partial pressure of carbon dioxide above the solution is reduced

d)

atmospheric nitrogen molecules displace carbon dioxide molecules

15.

What is the molality of a solution prepared by dissolving 86.9 g of diethyl ether, C4H10O, in 425 g of benzene, C6H6

a)

0.362 m

b)

0.498 m

c)

2.01 m

d)

2.76 m

16.

The mole fraction of potassium nitrate in an aqueous solution is 0.0194. The solution's density is 1.0627 g/mL. Calculate the molarity of the solution

a)

0.0194 M

b)

0.981 M

c)

1.05 M

d)

1.96 M

17.

Colligative properties depend on

a)

the chemical properties of the solute

b)

the chemical properties of the solvent

c)

the masses of the individual ions

d)

the number of particles dissolved

18.

From the following list of aqueous solutions and water, select the one with the lowest freezing point.

a)

0.75 m (NH4)3PO4

b)

1.0 m CaSO4

c)

1.0 m LiClO4

d)

1.5 m CH3OH

19.

Human blood has a molar concentration of solutes of 0.30 M. What is the osmotic pressure of blood at 25 oC?

a)

0.012 atm

b)

0.62 atm

c)

6.8 atm

d)

7.3 atm

20.

An emulsion is a dispersion consisting of a

a)

solid in a liquid

b)

liquid in a liquid

c)

gas in a liquid

d)

liquid in a solid