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Chem 1C Midterm #2 Review

Total questions: 10

Worksheet time: 15mins

Name
Class
Date
1.

For a first-order reaction, a plot of __________ versus __________ is linear.

a)

ln [A]t, t

b)

1/[A]t , t

c)

In [A]t, 1/t

d)

[A]t, t

e)

t, 1/[A]t

2.

Of the following, __________ will lower the activation energy for a reaction.

a)

increasing the concentrations of reactants

b)

adding a catalyst for the reaction

c)

raising the reaction temperature

d)

removing products as the reaction proceeds

e)

increasing the pressure

3.

Consider the reaction:

S2Cl2(l) + CCl4(l) → CS2(g) + 3 Cl2(g) ∆H˚ = 84.3 kJ

If the above reactants and products are contained in a closed vessel and the reaction system is at equilibrium, the number of moles of CS2 can be increased by

a)

adding some S2Cl2

b)

removing some CCl4

c)

decreasing the size of the reaction vessel

d)

increasing the temperature of the reaction system

e)

adding some Cl2

4.

Consider the general dissociation of an acid:

HA(aq) ↔ H+(aq) + A-(aq)

Select the true statement(s):

a)

Increasing the concentration of A- will increase HA dissociation

b)

The stronger the H-A bond, the weaker the acid

c)

The stronger the H-A bond, the stronger the acid

d)

The stronger the H-A bond, the easier it will dissociate

e)

The stronger the H-A bond, the harder it will be to dissociate

5.

Which of the following ions will act as a weak base in water?

a)

ClO-

b)

Cl-

c)

NO3-

d)

OH-

e)

None of the above

6.

Which of the following can be applied when solving for the pH of following dissociation:

HF(aq)+ H2O(l) ↔ H3O+(aq) + F-(aq)

a)

Strong acid approximation, when percent ionization is >100%

b)

Weak acid approximation, when percent ionization is <5%

c)

Weak acid approximation, when percent ionization is >5%

d)

Weak base approximation, when percent ionization is <5%

7.

Select from the following: the solution(s) in which you would have to consider the autoionization of water?

a)

HF and F-, at pH = 6.20

b)

HCN and CN-, at pOH = 6.40

c)

KF, at pH = 8.00

d)

None of the above

8.

Which of the following statements is incorrect?

a)

HNO3 added to a solution of CaC2H3O2 lowers the pH

b)

NaBr added to a solution of HBr increases the pH

c)

NaC2H3O2 added to a solution of HC2H3O2 increases the pH

d)

CaCl2 added to an HCl solution does not alter the pH

e)

KNO3 added to an HCl solution does not alter the pH

9.

A solution that contains a weak acid and its conjugate base in roughly equal concentrations is __________

a)

neither acidic or basic

b)

a heterogeneous mixture

c)

a half-acid solution

d)

neutral

e)

a buffer

10.

The value of Ka for HSO4- is 1 × 10−2. What is the value of Kb for SO42−?

a)

Kb = 1 × 10−12

b)

Kb = 1 × 10−8

c)

Kb = 1 × 10−2

d)

Kb = 1 × 102

e)

Kb = 1 × 105