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Thermo REVIEW

Total questions: 25

Worksheet time: 1hrs 18mins

Name
Class
Date
1.
What type of reaction is shown in the reaction pathway?
a)
endothermic reaction
b)
exothermic reaction
2.

How do you calculate Enthalpy of a reaction?

a)

ΔH = ΔHproducts - ΔHreactants

b)

ΔT = q / mC

c)

ΔG = ΔH -TΔS

d)

E = mc2

3.

Which statement is true regarding ENDOTHERMIC reactions?

a)

Temperature change is positive and enthalpy change is positive

b)

Temperature change is positive and enthalpy change is negative

c)

Temperature change is negative and enthalpy change is positive

d)

Temperature change is negative and enthalpy change is negative

4.

The enthalpy change is a negative (-) value, what side of the equation will the energy value be on.

a)

Reactants

b)

Products

5.
What type of reaction is shown in the reaction pathway?
a)

endothermic reaction

b)

exothermic reaction

6.

In the Image, will the heat (+177.8 KJ) be a product or a reactant?

a)

Product

b)

Reactant

7.

Define the term Exothermic by picking the correct statements. (Choose 3)

a)

Products have less energy than the reactants

b)

ΔH is negative

c)

ΔH is positive

d)

Energy is given out to the surroundings (temperature goes up).

e)

products have more energy than the reactants

8.

Define Endothermic by picking the correct statements. (Choose 3)

a)

ΔH is positive

b)

Energy is taken in from the surroundings (temperature goes down).

c)

Energy is given out to the surroundings (temperature goes up).

d)

· Products have less energy than the reactants

e)

products have more energy than the reactants

9.

Is this equation endo- or exo-thermic?

PCl3 (s) + Cl2 (g) --> PCl5 (s) + energy

a)

endothermic

b)

exothermic

10.
As 120 g of hot milk cools in a mug, it transfers 20, 000 J of heat to the environment. What is the temperature change of the milk? The specific heat of milk is 2.6 J/g·°C. (Q=mcΔT)
a)
64 °C
b)
1.56 °C
c)
640 °C
d)
cannot be determined
11.

How much heat in KJ does an aluminum block absorb if 100.0 grams are heated from 25.0oC to 50.0oC? the specific heat of aluminum is 0.900J/goC

a)

4.5 KJ

b)

-4.5 KJ

c)

2.25 KJ

d)

-2.25 KJ

12.
If 25 J are required to change the temperature of 5.0 g of substance A by 2.0°C, what is the specific heat of substance A? 
a)
250 J/g C
b)
10 J/g C
c)
63 J/g C
d)
2.5 J/g C
13.

A sample of iron receives 50.J of heat energy that raises the temperature of the iron by 25.0°C. If iron has a specific heat of 0.10 J/g°C, what is the mass of the iron sample?

a)

25g

b)

30g

c)

20g

d)

50g

14.

Based on the information in the table above, which of the following expressions gives the approximate ΔH° for the reaction represented by the following balanced chemical equation?

Fe2O3(s)+3 CO(g)→2 Fe(s)+3 CO2(g)

a)

ΔH°rxn=[(0kJ/mol)+(−394kJ/mol)]−[(−826kJ/mol)+(−111kJ/mol)]

b)

ΔH°rxn=[2(0kJ/mol)+ 3(−394kJ/mol)]−[(−826kJ/mol)+ 3(−111kJ/mol)]

c)

ΔH°rxn=[(−826kJ/mol)+ 3(−111kJ/mol)]−[2(0kJ/mol)+ 3(−394kJ/mol)]

d)

ΔH°rxn=[(−826kJ/mol)+(−111kJ/mol)]−[(0kJ/mol)+(−394kJ/mol)]

15.

Calculate the enthalpy of reaction (ΔH).

4CO2 (g) + 6H2O (g) → 2C2H6 (g) + 7O2 (g)


ΔHfo [CO2(g)] = -393.5 kJ

ΔHfo [H2O(g)] = -241.8 kJ

ΔHfo [C2H6(g)] = -84.7 kJ

a)

550.647 KJ/mol

b)

2855.584 KJ/mol

c)

-550.647 KJ/mol

d)

-2855.584 KJ/mol

16.

Consider the following equations.


Mg(s) + O2(g) → MgO(s) ∆H = –602 kJ

H2(g) + O2(g) → H2O(g) ∆H = –242 kJ


What is the ∆H value (in kJ) for the following reaction?


MgO(s) + H2(g) → Mg(s) + H2O(g)

a)

-844

b)

-360

c)

+360

d)

+844

17.

The enthalpies of combustion of C(s), H2(g) and C4H9OH(l) (in kJmol-1) are as follows  
C(s) + O2(g)   ->  CO2(g)                                               ∆H=a
H2(g) + ½O2(g)   ->   H2O(l)                                        ∆H=b
C4H9OH(l) + 6O2(g)   ->   4CO2(g) + 5H2O(l)   ∆H=c
What is the enthalpy change for the reaction shown below?
  4C(g) + 5H2(l) + ½O2(g)   ->   C4H9OH(l)

a)

c – 4a – 5b

b)

2a + 10b - c

c)

4a + 5b - c

d)

2a + 5b + c

18.

4 NH3 (g) + 5 O2 (g) ⟶ 4 NO (g) + 6 H2O (g)

Using the following information, calculate ΔH for the reaction shown above:

N2 (g) + O2 (g) ⟶ 2 NO (g) ΔH = -180.5 kJ

N2 (g) + 3 H2 (g) ⟶ 2 NH3 (g) ΔH = -91.8 kJ

2 H2 (g) + O2 (g) ⟶ 2 H2O (g) ΔH = -483.6 kJ

a)

256.0 kJ

b)

-1628.2 kJ

c)

-6387 kJ

d)

None of these

19.

The enthalpy of reactions for the synthesis two oxides of phosphorus are:

P4(s) + 3O2(g) → P4O6(s) ΔHf = –1600 kJ mol–1

P4(s) + 5O2(g) → P4O10(s) ΔHf = –3000 kJ mol–1

What is the enthalpy change, in kJ mol–1, for the reaction below?

P4O6(s) + 2O2(g) → P4O10(s)

a)

+4600

b)

+1400

c)

–1400

d)

–4600

20.
What is the specific heat of an unknown substance if 100.0 g of it at 200.0 °C reaches an equilibrium temperature of 27.1 °C when it comes in contact with a calorimeter of water.  The water weighs 75. g and had an initial temperature of 20.00 °C?  (Specific heat of water is 4.18 J/g°C) (show your work)
a)
0.111 J/g°C
b)
1.29 J/g°C
c)
0.129 J/g°C
d)
22225.85 J
21.

A piece of metal with a mass of 32.8 g is heated to 100.5°C and dropped into 138.2 g of water at 20.0°C.  The final temperature of the system is 30.2°C.  What is the specific heat capacity of the metal? (show your work)

a)

2.56 J/g°C

b)

0.391 J/g°C

c)

5.29 J/g°C

d)

3.50 J/g°C

22.

What does ΔT\Delta T  represent?

a)

tf −tit_{f\ }-t_i  

b)

ti −tft_{i\ }-t_f  

c)

t - celsius

d)

celsius - t

23.

How much energy must be used to produce 4.75 mol of gaseous water?

H2O (l) + 44.0 kJ --> H2O (g)

(Remember, coefficient of 1 = 1 mole)

a)

207 kJ

b)

9.36 kJ

c)

206.8 kJ

d)

9.362 kJ

24.

300 mL of water at 95 ºC are added to 700 mL of water at 62.8 ºC. What is the final temperature of the full liter of water?

a)

50 ºC

b)

85.6 ºC

c)

72.5 ºC

d)

94.2 ºC

25.
What mass of P4 must be reacted to produce 5905 kJ of energy?
P4 + 6Cl2 --> 4PCl3 + 2439 kJ
a)
25.43 g
b)
563.0 g
c)
2.421 g
d)
300.0 g