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Org Chem Reviewer Part 2

Total questions: 25

Worksheet time: 6hrs 15mins

Name
Class
Date
1.

A non-polar bond will be broken or cleaved

a)

heterolytically

b)

homolytically

2.

Hydrocarbons are polar in nature. They are soluble in water

a)

Only the first statement is true

b)

Only the second statement is True

c)

Both statements are true

d)

None of the statements are true

3.

cis-butene and trans-butene are

a)

functional isomers

b)

chain isomers

c)

geometric isomers

d)

positional isomers

e)

not isomers

4.

These are conformational isomers that are non-superimposable

a)

enantiomers

b)

diastereomers

c)

functional isomers

d)

optical isomers

5.

Which of the following compound is most soluble in water?

a)

Hexanol

b)

Hexane

c)

Hexene

d)

Hexanoic acid

e)

Hexanone

6.

Which of the following is with the lowest melting point and boiling point

a)

Octene

b)

Heptene

c)

Hexene

d)

Pentene

e)

butene

7.

Which of the following has the highest melting point?

a)

heptane amine

b)

heptanoic acid

c)

heptanol

d)

heptanal

8.

Which of the following has the highest solubility in water?

a)

pentanol

b)

2-methyl butanol

c)

2,2-dimethyl propanol

9.

Salicylic acid melts at a lower temperature than benzoic acid because it...

a)

is less polar

b)

can exhibit intra-molecular H-bonding

c)

is more branched

d)

It contains 2 polar groups

10.

Methoxy methane and ethanol are

a)

geometric isomer

b)

functional isomer

c)

chain isomer

d)

positional isomer

11.

Optical activity is brought about by the presence of

a)

carbon with a double bond

b)

carbon with 4 different groups attached to it

c)

chiral center

d)

B & C

e)

All of the given

12.

This is an isomer that rotates plane polarized right to the left

a)

cis

b)

trans

c)

E isomer

d)

levorotatory

e)

dextrorotatory

13.

If a bond between H and Cl leaves, the cleavage will most likely

a)

homolytic

b)

heterolytic

14.

This is an intermediate with a carbon having unpaired electron

a)

carbanion

b)

carbocation

c)

free-radical

15.

Among the organic compounds, the most soluble in water is

a)

alcohols

b)

amines

c)

aldehydes

d)

ketones

e)

Carboxylic acids

16.

Which of the following is the least reactive?

a)

propane

b)

propene

c)

propyne

17.

Which of the two have a higher melting point?

a)

pentane

b)

pentene

18.

Which of the following has the highest melting and boiling point?

a)

phenol

b)

salicylic acid

c)

benzoic acid

19.

Organic compounds are flammable and reacts with oxygen in the air. Organic compounds are soluble in water

a)

Only the first statement is correct

b)

Only the second statement is correct

c)

both of the statement are correct

d)

none of the statements are correct

20.

The more polar the organic compound, the higher is its melting point. The greater the tendency of the organic molecule to undergo H-bonding, the higher is its melting point

a)

Only the first statement is true

b)

Only the second statement is true

c)

Both of the statements are true

d)

None of the statements are true

21.

When the C-Cl bond breaks in CH3Cl, the intermediate formed will be a...

a)

free-radical

b)

carbocation

c)

carboanion

22.

The more stable conformational isomer of ethane is

a)

eclipsed

b)

staggered

23.

The more stabke isomer of cyclohexane is

a)

Boat

b)

Chair

c)

Bus

d)

Table

24.

The most stable free-radical is

a)

Primary

b)

Secondary

c)

Tertiary

d)

Depende sa araw

25.

Intra-molecular H-bonding decreases the inter-molecular attractive forces between molecules

a)

True

b)

False

c)

Maybe