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Pharmaceutical analysis- part1+2

Total questions: 45

Worksheet time: 57mins

Name
Class
Date
1.

Described as the number of gram or mole equivalents of solute present in one litre of a solution. When we say equivalent, it is the number of moles of reactive units in a compound.

a)

molarity

b)

ppm

c)

molality

d)

normality

2.

---------------is defined as the moles of a solute per liters of a solution.

a)

Molarity

b)

molality

c)

ppm

d)

normality

3.

Quantitative determination principle in titrimetric methods are based…

a)

On the basis of measurement of

Volume

b)

On the basis of absorbance of

sample

c)

On the basis of pharmacological

response

d)

On the basis of measurement of

conductance

4.

A molal solution contains 1 mole of solute per one

kilogram of solution ( 1 lit. of solvent) is called as

a)

Molality.

b)

molarity

c)

normality

d)

ppm

5.

Volumetric Analysis is a

a)

Qualitative method

b)

Quantitative method

c)

Semi quantitative method

d)

Both A and B

6.

The approximate molecular weight of NaOH is

a)

50g/mol

b)

20g/mol

c)

40g/mol

d)

35g/mol

7.

The quantity of NaOH pellets required to prepare 0.05 M, 100 ml standard solution is

a)

4 g

b)

2 g

c)

0.2 g

d)

0.02 g

8.

Volumetric analysis is a quantitative analysis

a)

False

b)

True

9.

The name of the apparatus used for holding the titrant is__________

a)

Conical flask

b)

Burette

c)

Pipette

d)

Volumetric flask

10.
What is the endpoint of a titration
a)
Where the amount of acid and base are equal as shown by a colour change 
b)
Where there is no base
c)
When the volume of base in the burette is used up 
d)
When there is no acid
11.
A qualitative test will reveal....
a)
identity of a material
b)
amount of a sample
c)
usefulness of a compound
d)
purity of a substance
12.
What is the molarity of 4 g of NaCl (MM=58.45) in 3,800 mL of solution?
a)
0.018 M
b)
0.0011 M
c)
1.052 M
d)
0.062 M
13.
How many grams of solute are dissolved in 125.0 mL of 5.00 M NaCl (MM = 58.45)?
a)
0.625 g NaCl
b)
625 g NaCl
c)
36.5 g NaCl
d)
0.04 mol NaCl
14.
True or False? The higher the concentration of a solution the less solutes it has in it.
a)
True
b)
False
15.
How many grams of AgNO3 (MM = 169.87) are needed to prepare 0.125M solution in 250 mL of water? 
a)
.03g
b)
0.5g
c)
5.3g
d)
84.9g
16.
What is the molarity of a solution made by diluting 26.5 mL of 6.00M HNO3 to a volume of 250 mL?
a)
15.9 M
b)
0.636 M
c)
0.642 M
d)
1.59 M
17.
How many mL of 10.8M HCl are required to make 100.0 mL of 3.00M acid?
a)
27.8 mL
b)
27.78 mL
c)
2.8 mL
d)
278 mL
18.
Molarity is measured in
a)
moles per kg
b)
mols per L
c)
moles per kJ
d)
moles per mL
19.

number of gram equivalent of solute dissolved in 1 litre of solution is

(a)  

20.
Molality is measured in
a)
mols per L
b)
mols per kg
c)
mols per kJ
d)
mols per mL
21.

Which of the following is NOT a property of Primary Standard?

a)

very pure

b)

less reactive

c)

high molecular weight

d)

hygroscopic

22.

It is prepared in the laboratory for a specific analysis. It is usually standardized against a primary standard.

a)

secondary analysis

b)

primary solution

c)

secondary standard

d)

primary standard

23.

Secondary standard are highly pure than primary standard?

a)

true

b)

false

24.

The number of gms of solute per 100 ml of solvent is known as

a)

Normality

b)

% weight by volume

c)

Molality

d)

Mole fraction

25.

What is the requirement for primary standard solution ?

a)

The substance should be unaltered in air during weighing.

b)

The substance should be hygroscopic.

c)

The substance should be hard to obtain.

d)

The substance should have less molecular weight.

26.

How close a measurement is to the true value is called..

a)

Accuracy

b)

Precision

c)

Significant

d)

Estimate

27.
This bullseye demonstrates...
a)
High Accuracy & High Precision
b)
High Accuracy & Low Precision
c)
Low Accuracy & High Precision
d)
Low Accuracy & Low Precision
28.
When a measurement is repeatable and consistent it is said to have...
a)
High precision
b)
Low precision
c)
High accuracy
d)
Low accuracy
29.
A set of data are all close to each other, but they are not close to the actual value.  This set of data can be described as...
a)
accurate
b)
precise
c)
both precise and accurate
30.
A set of data are not close to each other, but the average of the data is very close to the actual value.  This set of data can be described as...
a)
accurate
b)
precise
c)
both precise and accurate
31.
It is a measure of how close measurements come to each other when they are made in the same way
a)
Accuracy
b)
Precision
c)
Error
d)
Extrapolation
32.

Measurements: 12.3, 14.5, 10.1, 16.9

True Value: 25.0

These measurements are…

a)

Accurate, but not precise

b)

Precise, but not accurate

c)

Both precise and accurate

d)

Neither precise nor accurate

33.

Measurements: 24.9, 25.2, 25.1, 24.8

True Value: 25.0

These measurements are…

a)

Accurate, but not precise

b)

Precise, but not accurate

c)

Both precise and accurate

d)

Neither precise nor accurate

34.
?
a)
High Accuracy & High Precision
b)
High Accuracy & Low Precision
c)
Low Accuracy & High Precision
d)
Low Accuracy & Low Precision
35.
Volume?
a)
63.5 mL
b)
63 mL
c)
63.55 mL
d)
6 mL
36.
volume?
a)
48 mL
b)
48.2 mL
c)
48.25 mL
d)
4 mL
37.

Magnitude of difference between individual and true value of the quantity

a)

Gross error

b)

Percentage error

c)

Relative error

d)

Absolute error

38.

Number of significant figures in 4.0200 is

a)

5

b)

4

c)

3

d)

2

39.

Number of significant figures in 0.009407 is

a)

7

b)

6

c)

4

d)

3

40.

The number of significant digits in 0.032 is

a)

1

b)

2

c)

3

d)

4

41.

The number of significant digits in 410.00720 is

a)

5

b)

6

c)

7

d)

8

42.

An analyst measures the volume of a solution as 8.89ml, but the actual volume is 10ml. Calculate the absolute error and relative error. (Relative error = Absolute error/standard value)

a)

0.11 and 0.111

b)

0.11 and 0.011

c)

1.11 and 0.011

d)

1.11 and 0.111

43.

A person unable to judge the lower meniscus of burette at the endpoint during the titration comes under

a)

Error of the method

b)

Instrumental error

c)

Personal error

d)

Reagent error

44.

Please round-off the value 123.0012 to 3 signifiant digits after decimal:

(a)  

45.

Please round-off the value 123.001701 to 3 signifiant digits after decimal:

(a)