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Chemistry Laboratory Techniques 2

Total questions: 20

Worksheet time: 47mins

Name
Class
Date
1.

What is the term for process in which two immiscible liquids are mixed to transfer any chemical compound of interest from one phase to another?

a)

Filteration

b)

Distillation

c)

Liquid-Liquid Extraction

d)

Decanting

2.

Which of the following statements is FALSE about procedures for Liquid-liquid extraction

a)

Venting of the funnel is necessary to release built up pressure during shaking

b)

The effectiveness of extraction depends on the number of extractions

c)

NaCl is added into the sample if an emulsion is formed to separate the layers  

d)

Drying agents are added along with the sample inside the separatory funnel for maximum extraction

3.

Meshya dissolved 0.5g of Compound B in 20 mL of water and poured the solution in a separating funnel. She then added 10 mL of organic solvent, invert and left the mixture to stand for a few minutes. After the extraction, she found out that the distribution coefficient (Kpc) of Compound B between organic solvent / water is 8.33.

 

Which of the following represents the mass of Compound B that has transferred into the organic solvent?

a)

0.2043 g

b)

0.4023 g

c)

0.2034 g

d)

0.4032 g

4.

Which of the following is the correct formula to calculate the distribution coefficient (Kpc)?

a)

Kpc =

Concentration of solute in organic solvent /

Concentration of solute in water

b)

Kpc =

Concentration of solute in water /

Concentration of solute in organic solvent

c)

Kpc =

Concentration of solute in organic solution /

Concentration of solute in water

d)

Kpc =

Concentration of solute in water /

Concentration of solute in organic solution

5.

Which of the following completes the statement below?

“Inorganic substances dissolves in the ____________layer whereas organic compounds dissolves in the ____________layer.”

a)

inorganic; inorganic

b)

organic; organic

c)

inorganic; organic

d)

organic; inorganic

6.

Which of the following statements is FALSE about Soxhlet extraction

a)

The Soxhlet set-up is designed to perform continuous extraction automatically 

b)

Both condensation and evaporation help recirculate the solvent in the Soxhlet set-up

c)

The sample and boiling chips are placed in the round bottom flask fitted with the Soxhlet extractor and condenser

d)

None of the above

7.

What is the purpose of the siphon tube in the Soxhlet extractor?

a)

To ensure the continuous circulation of the solvent through the sample  

b)

To contain the sample throughout the extraction

c)

To collect the extracted sample

d)

All the above

8.

Steam distillation is a method of separating liquids immiscible in water and low volatility, at temperatures below their ______________

a)

Melting point

b)

Boiling point

c)

Triple point 

d)

Critical point

9.

To avoid the impurities from splashing over the distillate during steam distillation, distillation flask is sometimes attached with a ____________to avoid mixture contaminating the condenser.

a)

Claisen adapter

b)

Still head adapter

c)

Vacuum adapter

d)

Dropping funnel

10.

How is hot water introduced into the steam distillation set-up without the presence of the steam generator?

a)

Claisen funnel

b)

Dropping funnel

c)

Vacuum adapter 

d)

Still head adapter

11.

________________is a process which excess amount of standard solution used to react with the analyte is determined by titrating with another standard solution.

a)

Direct titration

b)

Potentiometric titration

c)

Back titration

d)

Complexometric titration

12.

Which of the following is a good reason for doing a back titration procedure?

a)

When the reaction is too slow

b)

When the standard solution is unstable when kept for longer periods

c)

Suitable indicators are unavailable

d)

All of the above

13.

In back titration, what is the role of the second titrant?

a)

To neutralise excess first titrant

b)

To react with the analyte

c)

Increases accuracy of the titration

d)

Establish endpoint of the titration

14.

How many potential sites for dative covalent bond that can be formed by EDTA?

a)

3

b)

4

c)

5

d)

6

15.

Which of the following statements is TRUE about the behaviour of oxalate (ox) in the complex shown?

a)

Oxalate ion is a monodentate ligand

b)

Oxalate ion is a bidentate ligand

c)

Oxalate ion is a tridentate ligand

d)

Oxalate ion is a tetradentate ligand

16.

Which formula is used to calculate for hardness of water when the sample was titrated against EDTA

a)

b)

c)

d)

17.

Examine the metal complex below.

Which of the following statements is TRUE?

a)

There is one ligand that forms six dative covalent bonds with the metal cation

b)

There are three ligands that each form two dative covalent bonds with the metal cation

c)

There are two ligands that each form three dative covalent bonds with the metal cation

d)

None of the above

18.

What is meant by “end point”?

a)

The point at which the amount of acid is sufficient to neutralise all the base

b)

The point at which a substance turns from solid to a liquid

c)

The point at which an indicator changes colour

d)

None of the above

19.

What is meant by “equivalence point”?

a)

The point at which an indicator changes colour

b)

The point at which a substance turns from solid to a liquid

c)

The point at which the amount of acid is sufficient to neutralise all the base

d)

None of the above

20.

The graph above shows which type of acid-base titration?

a)

Strong acid- strong base titration curve 

b)

Strong acid-weak base titration curve

c)

Weak acid-strong base titration curve

d)

Weak acid-weak base titration curve