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GALVANIC CELLS AND ELECTROYTIC CELLS

Total questions: 25

Worksheet time: 6hrs 15mins

Name
Class
Date
1.

In a Galvanic Cell, the anode is...

a)

positive

b)

negative

2.

Reduction occurs at the...

a)

anode

b)

cathode

3.

In a Galvanic cell, the electrons flow from the...

a)

anode to the cathode

b)

cathode to the anode

4.

Ecell =

a)

Ered - Eox

b)

Ered + Eox

c)

Eox - Ered

d)

Eox + Ered

5.

In a redox reaction, the oxidising agent... (choose two options)

a)

is oxidised

b)

is reduced

c)

increases its oxidation number

d)

decreases its oxidation number

6.

In a Galvanic Cell, the salt bridge...

a)

completes the circuit so that electrons can flow through the wire

b)

maintains charge balance

c)

is soaked in an unreactive electrolyte such as KNO3

d)

all of the above

7.

Consider the galvanic cell reaction Zn (s) + Cu2+ (aq) → Cu (s) + Zn2+ (aq) When the cell is running spontaneously, which is the only true statement?

a)

The copper electrode loses mass and the zinc electrode is the cathode.

b)

The copper electrode gains mass and the copper electrode is the cathode.

c)

The zinc electrode gains mass and the zinc electrode is the anode.

d)

The zinc electrode loses mass and the zinc electrode is the cathode.

8.

A certain galvanic cell has for its spontaneous cell reaction: Zn + HgO → ZnO + Hg

Which is the half-reaction occurring at the anode?

a)

HgO + 2 e- → Hg + O2-

b)

Zn2+ + 2 e- → Zn

c)

Zn → Zn2+ + 2 e-

d)

ZnO + 2 e- → Zn

9.

Select all the standard conditions used to measure the standard electrode potentials:

a)

electrolyte solution 1 moldm-3

b)

298K temperature

c)

all chemicals in gaseous form

d)

1atm pressure

e)

standard hydrogen electrode as comparison

10.
Consider the galvanic cell given.
Which of the following deductions about this cell is correct?
a)
Oxidation is occurring in half-cell 2
b)
The positive electrode is in half-cell 2
c)
Oxidation is occurring in half-cell 1
d)
The negative electrode is in half-cell 1
11.

Reactions in galvanic cells are

a)

spontaneous, redox reactions

b)

non-spontaneous, redox reactions

c)

spontaneous, non-redox reactions

d)

non-spontaneous, non-redox reactions

12.

A VCE chemistry student sets up a galvanic cell using two standard half-cells with half reactions.

Half-cell 1: Cr3+(aq)+e-→Cr2+(aq)

Half-cell 2: Cr(s)→Cr2+(aq)+2e-

Using this information, we can determine that;

a)

Half-cell 1 is the anode, where oxidation occurs

b)

Half-cell 1 is the cathode, where reduction occurs

c)

No spontatneous reaction will occur, since only chromium is involved

d)

Cr3+ is the reductant, since it undergoes reduction

13.
What reaction occurs at the anode?
a)
Ag+ + e- →Ag
b)
Ag → Ag+ + e-
c)
Ni2+ + 2e- → Ni
d)
Ni → Ni2+ + 2e-
14.

Write the cell notation for a galvanic cell with a copper electrode and a zinc electrode.

a)

Cu(s) | Zn2+(aq) || Cu2+(aq) | Zn(s)

b)

Cu(s) | Cu2+(aq) || Zn2+(aq) | Zn(s)

c)

Zn(s) | Cu2+(aq) || Zn2+(aq) | Cu(s)

d)

Zn(s) | Zn2+(aq) || Cu2+(aq) | Cu(s)

15.

The cathode is ___________. 

Sn(s)|Sn(aq)2+‖Ag(aq)2+|Ag(s). 

a)

Sn 

b)

Sn2+ 

c)

Ag 

d)

Ag2+ 

16.

Which of the following statements is/are true? 

I. The electrons are transferred from Ag to Mg 

II. At the end of the reaction, the concentration of Ag+ decreases 

III. The mass of Mg would decrease during the course of the reaction 

Mg / Mg2+ // Ag+ / Ag 

a)

II and III only 

b)

I and II only 

c)

II only

d)

III only

17.
What are the features of a standard hydrogen electrode?
a)
I and II
b)
I and III
c)
II and III
d)
I, II and III
18.
Which represents reduction process occurring in standard hydrogen electrode?
a)
H2(g) → 2H+(aq) + 2e
b)
H+(aq) + OH(aq) → H2O(l)
c)
2H+(aq) + 2e → H2(g)
d)
O2(g) + 4H+(aq) + 4e– → 2H2O(l)
19.
Which statement is correct about value of Eο?
a)
more positive value Eο, greater driving force for reduction
b)
more negative value Eο, greater driving force for reduction
c)
more positive value Eο, greater the rate of reaction
d)
more negative value Eο, greater the rate of reaction
20.
Which statement is correct?
a)
Ca2+ can oxidize Ni
b)
Ni2+ can reduce Ca2+
c)
Fe3+ can oxidize Ni
d)
Fe3+ can reduce Ca2+
21.

What ions are present in molten aluminium oxide?

a)

Al3+, O2-, H+, OH-

b)

Al3+, O2-

c)

Al3+, OH-

22.
What particle carries the charge in the wire?
a)
electron
b)
proton
c)
ion
d)
atom
23.
Which statement correctly describes the 2 electrodes?
a)
The anode is negative and the cathode is positive
b)
The anode and cathode are both positive
c)
The anode is positive and the cathode is negative
d)
The anode and cathode are both negative.
24.
What is the equation to show what happens to Cl ions at the anode.
a)
Cl- --> Cl + e-   
b)
2Cl- --> Cl2 + 2e-   
c)
Cl2 + 2e-   2Cl- 
d)
Cl2 + 2e-  -->  2Cl- 
25.

If the fork is to be electroplated with silver metal, what electrolyte should be used?

a)

Molten silver chloride

b)

Aqueous silver nitrate

c)

Sodium chloride solution

d)

Copper(II) sulphate solution