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TG-2

Total questions: 12

Worksheet time: 11mins

Name
Class
Date
1.

Choose the correct statement regarding the energy levels of hydrogen-like atoms:

a)

the ground state corresponds to the 2s¹ electronic configuration

b)

the energy of the 2p orbital is higher than that of the 2s orbital

c)

the energy of the 2s orbital is higher than that of the 2p orbital

d)

all 3s, 3p, and 3d orbitals have the same energy

2.

Choose the correct statement regarding the radial wavefunction R(r) in hydrogen-like atoms:

a)

It is maximum when

r → 0 for s-type orbitals

b)

The orbital 2p has 2 radial nodes

c)

It is maximum when

r → 0 for p-type orbitals

d)

The orbital 2p has 1 radial node

3.

Choose the correct statement regarding the angular wavefunction, γ(θ,φ),of the hydrogen-like atoms:

a)

The number of angular nodes is n (principal quantum number)

b)

The orbital 2s has 1 angular node

c)

The orbital 2p has no angular nodes

d)

The number of angular nodes is l (angular momentum quantum number)

4.

Which of the following combinations of quantum numbers is not correct?

a)

n = 1

l = 0

ml = 0

b)

n = 3

l = 3

ml = 0

c)

n = 4

l = 3

ml = -1

d)

n = 2

l = 0

ml = 0

5.

Choose the correct statement regarding the energy of orbitals in multielectronic atoms:

a)

All orbitals in the same electronic shell have the same energy

b)

All orbitals in the same electronic sub-shell have the same energy

c)

Orbitals in 2p sub-shell have lower energy than those in the 2s sub-shell

d)

Sub-shell 3d has 3 energetically degenerated orbitals

6.

The atomic radius decreases as we move from left to right across a period in the Periodic Table because:

a)

The atom's electronegativity increases

b)

The atom's electronegativity decreases

c)

Inter-electronic repulsion decreases

d)

The effective nuclear charge (Zeff) increases

7.

Choose the correct answer regarding the C-O bond order in CO₂ and [CO₃]²⁻

a)

Both compounds have the same C-O bond order

b)

The C-O bond order in CO₂ is greater than in [CO₃]²⁻

c)

The C-O bond order in CO₂ is less than in [CO₃]²⁻

d)

The C-O bond order in CO₂ is 1.5 and in [CO₃]²⁻ it is 1.33

8.

The molecular geometry of XeOF4 molecule is:

a)

Trigonal bipyramidal

b)

Octahedral

c)

"see-saw" geometry

d)

Square Pyramidal

9.

Gillespie geometry (electron group geometry) of XeO2F2 is:

a)

AX4E

b)

AX4

c)

AX4E2

d)

AX3E2

10.

Indicate which of the following molecules is polar:

a)

PCl5

b)

CO2

c)

PCl3

d)

C2H4

11.

In the PCl₂F₃ molecule, experiments find:

a)

wo different P-Cl distances and two different P-F distances

b)

One P-Cl distance and one P-F distance

c)

Two different P-Cl distances and three different P-F distances

d)

One P-Cl distance and two different P-F distances

12.

From the molecular orbital diagrams of O₂, O₂²⁻, and O₂²⁺, we can determine that:

a)

Only O₂ is paramagnetic

b)

Both O₂ and O₂²⁻ are paramagnetic

c)

Both O₂ and O₂²⁺ are paramagnetic

d)

None of the three compounds is paramagnetic