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MOLECULAR ORBITAL DIAGRAM

Total questions: 12

Worksheet time: 3hrs 0mins

Name
Class
Date
1.

Bonding molecular orbitals possess ---------------electron density .

a)

Low

b)

moderate

c)

Higher

2.

Every electron in the anti bonding molecular orbital makes its contribution to the ---------- of two combining atoms.

a)

Repulsion

b)

Attraction

c)

Stability

d)

Same sign

3.

Can you predict the molecule? Justify your answer

a)

A. N2

b)

B. F2

c)

C. O2

4.

Para magnetic or diamagnetic?

a)

A. Paramagnetic

b)

B.. Diamagnetic

5.

Can you predict the molecule? Justify your answer

a)

A. N2

b)

B. F2

c)

C. O2

6.

The electron configuration of a particular diatomic species is (σ2s)2(σ*2s)2(σ2p)2(π2p)2(π*2p)4. What is the bond order for this species?

a)

1.5

b)

1

c)

0.5

d)

0

e)

2

7.

following mo diagram represents which molecule?

a)

N2

b)

O2

c)

F2

d)

none of these

8.

what are the bond orders in O2, O2+,O2-

a)

2, 3,4

b)

2,1.5,2.5

c)

2,2.5,1.5

d)

2.5,2,1.5

9.

A π (pi) bond is the result of the

a)

overlap of two s orbitals

b)

overlap of an s orbital and a p orbital

c)

overlap of two p orbitals along their axes

d)

sidewise overlap of two parallel p orbitals

e)

sidewise overlap of two s orbitals

10.

When comparing Be2 and H2:

I.Be2 is more stable because it contains both bonding and antibonding valence electrons.

II.H2 has a higher bond order than Be2.

III.H2 is more stable because it only contains σ1s electrons.

IV.H2 is more stable because it is diamagnetic, whereas Be2 is paramagnetic.

a)

I, II

b)

III only

c)

II, III

d)

II, IV

e)

III, IV

11.

Rank the energy of a bonding MO in comparison to its atomic orbital.

a)

higher

b)

lower

c)

equal

12.

BMO is formed due to

a)

Constructive Interference

b)

Destructive Interference

c)

Different sign of wave function

d)

Both 2 & 3