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Unit 9 quick review

Total questions: 16

Worksheet time: 12mins

Name
Class
Date
1.

Entropy is always ________ in the Universe

a)

increasing

b)

decreasing

c)

constant

2.

Which has the HIGHEST entropy change?

a)

1 --> 2 particles

b)

gas --> liquid

c)

solid --> gas

d)

low to high temperature (same phase)

3.

Which has a positive sign for S?

a)

2Na (s) + Cl2 (g) --> 2NaCl (s)

b)

H2O (g) --> H2O (l)

c)

H+ (aq) + NO3- (aq) --> HNO3 (l)

d)

CaCl2 (s) --> Ca2+ (aq) + 2Cl- (aq)

4.

Which has a negative sign for S?

a)

water evaporating

b)

NaCl dissolving in water

c)

water freezing

d)

sublimation of CO2

5.

reaction is ALWAYS spontaneous

a)

- H, - S

b)

+ H, + S

c)

+ H, - S

d)

- H, + S

6.

a reaction that is exothermic and has a decrease in entropy is

a)

spontaneous at high temps

b)

spontaneous at low temps

c)

always spontaneous

d)

never spontaneous

7.

enthalpy is driving force when

a)

exothermic

b)

endothermic

c)

increase in entropy

d)

decrease in entropy

8.

Which of the following substances is expected to have the largest standard molar entropy?

a)

H2O(l)H_2O\left(l\right)

b)

H2O(g)H_2O\left(g\right)

c)

H2O2(l)H_2O_2\left(l\right)

d)

H2O2(g)H_2O_2\left(g\right)

9.

The diagrams represent molecular views of the three phases of water. Information contained in the diagrams can be used to explain which of the following?

i. Why ice floats on water.

ii. Why the gas phase is more compressible than the liquid phase.

iii. Why ice melts under pressure

a)

i only

b)

ii only

c)

iii only

d)

i, ii, and iii

10.

Which equation correctly represents the free energy change in a chemical reaction?

a)

ΔG = ΔH + TΔS

b)

ΔG = ΔH - TΔS

c)

ΔG = ΔT - ΔHΔS

d)

ΔG = ΔS - TΔH

11.

If a process is exothermic and not spontaneous, then what MUST be true?

a)

ΔS > 0

b)

ΔH > 0

c)

ΔG = 0

d)

ΔS < 0

12.

Which tendencies favor a spontaneous reaction?

a)

decreasing enthalpy and decreasing entropy

b)

decreasing enthalpy and increasing entropy

c)

increasing enthalpy and decreasing entropy

d)

increasing enthalpy and increasing entropy

13.
Entropy always increases when
a)
enthalpy decreases.
b)
temperature decreases.
c)
temperature increases.
d)
volume increases.
14.

For a reaction to be spontaneous, the Gibbs free energy must be _______

a)

positive

b)

neutral

c)

negative

d)

zero

15.

The reaction will be ________ if the enthalpy of reaction is negative and entropy is positive

a)

spontaneous

b)

non spontaneous

16.

Which of the following has a higher entropy?

a)

carbon monoxide

b)

carbon dioxide