WorksheetsCHEM 140 Chapter 5 & 6
Total questions: 64
Worksheet time: 32mins
Same formula - different connectivity
Constitutional Isomers
Stereo Isomers
Same formula & same connectivity - different arrangement
Constitutional Isomers
Stereo Isomers
Enantiomers & Diastereomers
Constitutional Isomers
Stereo Isomers
mirror images
Enantiomers
Diastereomers
not mirror images
Enantiomers
Diastereomers
A
Same compound
Constitutional Isomer
Steroisomer
Enantiomer
Diastereiomer
B
Same compound
Constitutional Isomer
Steroisomer
Enantiomer
Diastereiomer
C
Same compound
Constitutional Isomer
Steroisomer
Enantiomer
Diastereiomer
D
Same compound
Constitutional Isomer
Steroisomer
Enantiomer
Diastereiomer
E
Same compound
Constitutional Isomer
Steroisomer
Enantiomer
Diastereiomer
has a plane of symmetry (exact mirror images)
Chiral
Achiral
No chiral centers
Chiral
Achiral
meso compounds
Chiral
Achiral
Superimposable (can be lined exactly over itself)
Chiral
Achiral
has a chiral center
Chiral
Achiral
no plane of symmetry
Chiral
Achiral
non-superimposable or enantiomer (cant be lined exactly over its self)
Chiral
Achiral
R
Clockwise
Counter clockwise
S
Clockwise
Counter clockwise
A compound exhibiting a positive rotation (+)
Dextrorotatory
Levorotatory
A compound exhibiting a negative rotation (-)
Dextrorotatory
Levorotatory
refer to the configuration (3D arrangement) of a chiral center
R / S
+ / -
independent of conditions
R / S
+ / -
refer to the direction in which plane polarized light is rotated
R / S
+ / -
dependent on conditions
R / S
+ / -
breaking bonds require energy
Enthalpy (ΔH)
Kinetics
Entropy
the exchange of energy / heat between a system & its surroundings under constant pressure
Enthalpy (ΔH)
Kinetics
Entropy
the study of reaction rates
Enthalpy (ΔH)
Kinetics
Entropy
disorder associated with a system
Enthalpy (ΔH)
Kinetics
Entropy
determines whether a reaction can occur
Enthalpy (ΔH)
Kinetics
Entropy
change in _____ for both system & surrounding must be considered
Enthalpy (ΔH)
Kinetics
Entropy
Homolytic Bond Cleavage
Heterolytic Bond Cleavage
Homolytic Bond Cleavage
Heterolytic Bond Cleavage
energy required to break a covalent bond via homolytic bond cleavage
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
AKA total change in enthalpy
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
AKA heat of reaction
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
result of a collision between reactants
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
ΔG must be negative
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
reaction favors formation of products (thermodynamically favorable)
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
ΔG must be positive
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
reaction favors formation of reactants (thermodynamically unfavorable)
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
Total entropy must be positive (increase overall)
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
total entropy must be negative (decrease overall)
Bond Dissociation energy (ΔH°)
Reaction
Spontaneous Reaction/Process
Non Spontaneous Reaction/Process
system energy increases - received energy from surroundings
+ ΔH °
- ΔH °
endothermic
+ ΔH °
- ΔH °
system energy decreases - gave energy to surroundings
+ ΔH °
- ΔH °
exothermic
+ ΔH °
- ΔH °
large rate constant
fast reaction
slow reaction
small rate constant
fast reaction
slow reaction
low Ea
fast reaction
slow reaction
high Ea
fast reaction
slow reaction
1
rate constant
concentration of starting materials
2
rate constant
concentration of starting materials
the ability of an atom to distribute its electron density unevenly in response to external influences
Catalyst
Polarizability
increase in temp
decrease in temp
a compound that can speed up the rate of a reaction without being consumed
Catalyst
Polarizability
increase in temp
decrease in temp
Transition States
increase in rate
Catalyst
Polarizability
increase in temp
decrease in temp
Transition States
decrease in rate
Catalyst
Polarizability
increase in temp
decrease in temp
Transition States
the state which reaction passes
Catalyst
Polarizability
increase in temp
decrease in temp
Transition States
Kinetics (rate of reaction)
Thermodynamics (equilibrium)
Kinetics (rate of reaction)
Thermodynamics (equilibrium)
Blue
Transition States
Intermediates
green
Transition States
Intermediates
Exothermic
Endothermic
Exothermic
Endothermic
