

PENENTUAN ENTALPI REAKSI
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Chemistry
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11th Grade
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Hard
Siti Aminah
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PENENTUAN ENTALPI REAKSI
Kelas XI
Semester Ganjil
By Siti Aminah
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Amatilah reaksi berikut ini:
NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(L) ∆Ho = -177,8 kJ/mol
Diketahui :
∆HfoNaOH(aq) = -426,7 kJ mol-1 ∆HfoNaCl(aq) = -411,0 kJ mol-1
∆HfoHCl(aq) = -92,3 kJ mol-1
∆HfoH2O(l) = -285,8 kJ mol-1
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Apakah ada pertanyaan ????
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NaCl(aq) + H2O(l)
{(-411 kJ/mol) + (-285,8 kJ/mol)}
(-696,8 kJ/mol)
∆H hasil reaksi (produk)
NaOH(aq) + HCl(aq)
{(-426,7 kJ/mol)+ (-92,3 kJ/mol)}
(-519 kJ/mol)
∆H pereaksi
Berdasarkan data ∆Hfo hitunglah jumlah ∆H pereaksi dan jumlah ∆H hasil reaksi (produk)!
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Cara untuk menghitung ∆H reaksi adalah :
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∆H reaksi = ∑ ∆Hfo produk - ∑ ∆Hfo pereaksi
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Tugas Pilihan Ganda
Pilihlah satu jawaban yang anda anggap paling benar dengan cara memberi tanda silang (X) pada huruf A, B, C, D atau E!
1. Reaksi 3 gram logam magnesium dengan nitrogen berlebih menghasilkan Mg3N2. Jika pada keadaan standar, proses tersebut melepaskan kalor 28 Kj maka entalpi pembentukan standar Mg3N2 sebesar…. (Ar Mg = 24, N = 14)
A. – 461,5 kJ/mol
B. – 571,5 kJ/mol
C. – 671,5 kJ/mol
D. – 761,5 kJ/mol
E. – 771,5 kJ/mol
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2. Persamaan termokimia di bawah ini yang termasuk perubahan entalpi pembentukan standar adalah…
A. C2H4(g) + 3 O2(g) ⎯⎯→ 2 CO2(g) + 2 H2O(g)
B. Na(s) + ½ Cl2(g) ⎯⎯→ NaCl (s)
C. 2 NaOH(aq) + H2SO4(aq) ⎯⎯→ Na2SO4(aq) + 2 H2O(g)
D. H2O(s) ⎯⎯→ H2O(l)
E. H2O(l) ⎯⎯→ H2O(g)
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3. Entalpi pembentukan standar (DHfo) Fe2O3(s), Fe3O4(s), CO(g), dan CO2(g) berturut-turut yaitu, –822 kJ/mol, –1.120 kJ/mol, –110 kJ/mol, – 394 kJ/mol. Nilai entalpi yang menyertai reaksi :
3 Fe2O3(s) + CO(g) ⎯⎯→ CO2(g) + 2 Fe3O4(s) adalah….
A. – 582 kJ/mol
B. – 344 kJ/mol
C. – 116 kJ/mol
D. – 58 kJ/mol
E. – 26 kJ/mol
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II. Essay
Kerjakan soal-soal berikut!
1. Diketahui entalpi pembentukan NH4NO3(g), N2O(g) dan H2O(g) berturut-turut = –365,6 kJ; + 81,6 kJ; dan –241,8 kJ. Hitunglah perubahan entalpi dari reaksi :
NH4NO3(g) → N2O(g) + 2 H2O(g)
2. Diketahui ΔHf° H2CO3(aq) = –699,65 kJ/mol. Hitunglah besarnya perubahan entalpi pada penguraian 496 gram H2CO3 (Ar H = 1, C = 12, O = 16) dan tuliskan persamaan termokimia peruraian H2CO3!
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PENENTUAN ENTALPI REAKSI
Kelas XI
Semester Ganjil
By Siti Aminah
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