Le Chatelier's Principle and Solubility

At what time (in seconds) is equilibrium established?

• 0 seconds
• 1 second
• 5 seconds
• 10 seconds

For the reaction...
energy +  N_2(g)  +  O_2(g)  <−>  2NO_(g)
If  O_2(g) is removed, the  concentration of N₂ will _______.

• increase
• decrease
• remain the same
• double

For the reaction...
SO_2(g) + O_2(g) <−>  SO_3(g)
If the concentration of SO_2(g)  is increased, the equilibrium of the reaction will ___________.

• shift to the left
• shift to the right
• not shift

A +  B <--> C + D   ΔH= 151kJ
Rewrite the above equation with energy as a reactant or product:

• A +  B <--> C + D + energy
• A +  B + energy <--> C + D 

For the reaction...
heat  +  N_2(g)  +  O_2(g)  <−>  2NO_(g)
If the heat is removed to the chemical system, the equilibrium will _______.

• shift to the left
• shift to the right
• not shift

For the reaction...
N_{2 (g)} +  3 H_2 (g) <−> 2 NH_{3 (g)}

If the pressure in the system is increased, the reaction will __________________.

•  shift to the left
• shift to the right
• not shift

Given: 2A(g) <-> 2B(g) + C(g). At a particular temperature, K = 1.6x10⁴.
Raising the pressure by lowering the volume of the container will...

• cause [A] to increase
• cause [B] to increase
• have no effect
• cannot be determined

Which of the following shows the correct dissolution reaction for BaCl₂?

• Ba ²⁺(aq) + Cl₂^-(aq) -> BaCl₂(s)
• BaCl₂(aq) -> Ba ²⁺(aq) + 2Cl^-(aq)
•  BaCl₂(s) -> Ba ²⁺(aq) + 2Cl^-(aq)
• Ba ²⁺(aq) + 2Cl^-(aq) -> BaCl₂(s)

An unknown salt, M₂Z, has a K_sp of 3.3 x 10^-9. Calculate the solubility in mol/L of M₂Z.

• 2.9 x 10^-5 M
• 5.7 x 10^-5 M
• 9.4 x 10^-5 M
• 3.7 x 10^-5 M

The molar solubility of PbI₂ is 1.52 x 10^-3 M. Calculate the value of K_sp for PbI₂.

• 3.51 x 10^-9
• 1.40 x 10^-8
• 4.62 x 10^-6
• 1.52 x 10^-3