Claisen Condensation and Dieckmann Condensation

Claisen Condensation and Dieckmann Condensation

Assessment

Interactive Video

Chemistry, Science

11th Grade - University

Hard

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The video explains Claisen condensation, a reaction involving ester substrates and strong bases, leading to beta-dicarbonyl compounds. It covers the mechanism, including the importance of matching alkoxide groups to prevent transesterification. The video also discusses crossed Claisen condensation with different esters and introduces Dieckmann condensation, an intramolecular variant resulting in cyclization.

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10 questions

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1.

OPEN ENDED QUESTION

3 mins • 1 pt

What is the key difference between aldol condensation and Claisen condensation in terms of substrates?

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2.

OPEN ENDED QUESTION

3 mins • 1 pt

Explain the significance of matching alkoxide groups in Claisen condensation.

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3.

OPEN ENDED QUESTION

3 mins • 1 pt

What happens if the esters used in a crossed Claisen condensation do not have matching alkoxy groups?

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4.

OPEN ENDED QUESTION

3 mins • 1 pt

Describe the mechanism of Claisen condensation starting from the formation of the enolate.

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5.

OPEN ENDED QUESTION

3 mins • 1 pt

What is a beta-dicarbonyl compound and how is it formed in Claisen condensation?

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6.

OPEN ENDED QUESTION

3 mins • 1 pt

How does the presence of an alkoxide in solution affect the acidity of protons in the product of Claisen condensation?

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7.

OPEN ENDED QUESTION

3 mins • 1 pt

What is the role of aqueous acidic workup in the Claisen condensation process?

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