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Chapter 14 : Haloalkane

Total questions: 20

Worksheet time: 17mins

Name
Class
Date
1.
a)

tertiary amine

b)

alkane

c)

haloalkane

d)

alkene

2.
haloalkanes also called
a)
alkyl halides
b)
vinylic halides
3.
common name for methylbenzene…
a)
toluene
b)
alkyl halides
4.
Name this structure.
a)
1,1,2-trimethylcyclopropane
b)
1,2,2-trichlorocyclopropane
c)
1,1,2-trichlorocyclobutane
d)
1,1,2-trichlorocyclopropane
5.

Haloalkane is

a)

A non polar molecule

b)

A polar molecule

6.
Name this molecule:
a)
trifluoro-1-methylmethane
b)
1,1,1-trifluoromethane
c)
trifluorethane
d)
1,1,1-trifluoroethane
7.
Name this structure.
a)
3-chloropropane
b)
3-chloropentane
c)
Chloropentane
d)
Chloropropane
8.
Name this structure.
a)
1,3-dibromo-2-chlorobutane
b)
2,4-dibromo-3-chlorobutane
c)
1,3-bromo-2-chlorobutane
d)
2,4-bromo-3-chlorobutane
9.

mechanism for hydrolysis of iodoethane to ethanol by aqueous NaOH

a)

SN2

b)

SN1

10.

mechanism of hydrolysis of 2-chloro-2-methylpropane to 2-methyl-2-propanol

a)

SN1

b)

SN2

11.
summary reaction grignard reagent with methanal will produce
a)
→1° ROH
b)
→ RCOOH
12.
summary reaction grignard reagent with other aldehyde will produce
a)
→2° ROH
b)
→3° ROH
13.
summary reaction grignard reagent with ketone will produce
a)
→3° ROH
b)
→2° ROH
14.
summary reaction grignard reagent with CO2 will produce
a)
→ RCOOH
b)
→3° ROH
15.

The types of mechanism in topic halolakane :

a)

SN 1

b)

SN 2

c)

SN 1 & SN 2

d)

No idea

16.

SN2 is a ............step mechanism

a)

One

b)

Two

17.

The decreasing reactivity of haloalkane towards SN2 reaction

a)

1° > 2°> 3°

b)

3° > 2°> 1°

18.

Grignard reagent very useful. From R-X (haloalkane), when using grignard can form another compound such as (except):

a)

Primary, secondary & tertiary alcohol

b)

Acid carboxylic

c)

Alkane

d)

keton

19.

The product when R-X react with grignard reagent (Mg/ dry ether) :

a)

R-H (alkane)

b)

RMgX

c)

Mg-X

d)

R-X

20.

Preparation of Haloalkane (R-X) :

a)

Using alkane with bromonation & UV (Br2/UV)

b)

Using alkene with present of hydrogen bromide (HBr)

c)

Substitusion R-OH with PBr3

d)

All above