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IB Topic 10 Organic Chemistry

Total questions: 20

Worksheet time: 39mins

Name
Class
Date
1.

How many alcohols have the general formula C4H10O?

a)

3

b)

4

c)

5

d)

6

2.

What is the general formula of the alkyne series?

a)

CnHn

b)

CnH2n-2

c)

CnH2n

d)

CnH2n+2

3.

Which compound can both be esterified and turn acidified potassium dichromate(VI) solution green?

a)

(CH3)3COH

b)

CH3CH2CO2H

c)

(CH3)2CHOH

d)

CH3CH2COCH3

4.

What is the mechanism of the reaction between ethane and chlorine in sunlight?

a)

Free radical substitution

b)

Free radical addition

c)

Electrophilic substitution

d)

Electrophilic addition

5.

Which is propyl propanoate?

a)

CH3CH2CH2OOCCH2CH3

b)

CH3CH2CH2COOCH2CH3

c)

CH3CH2CH2COCH2CH3

d)

CH3CH2CH2OCH2CH2CH3

6.

Which are consecutive members of a homologous series?

a)

CH4, CH3Cl, CH2Cl2

b)

HCOOH, CH3COOH, C2H5COOH

c)

C2H2, C2H4, C2H6

d)

HCOOH, HCHO, CH3OH

7.

Which could form an addition polymer?

a)

H2NCH2CHCHCH2NH2

b)

H2N(CH2)6CO2H

c)

HO(CH2)2CO2H

d)

H2N(CH2)6NH2

8.

A compound decolorizes bromine water in the dark. Which statement is correct?

a)

It contains C=C and is an alkene.

b)

It contains C–C and is an alkene.

c)

It contains C=C and is an alkane.

d)

It contains C–C and is an alkane.

9.

Which compound could be X in the two-stage reaction pathway?

C2H4 → X → C2H5OH

a)

C2H6

b)

C2H3OH

c)

C2H5Br

d)

C2H4Cl2

10.

Applying IUPAC rules, what is the name of the compound?



a)

1-ethyl-1,3-dimethylbut-2-ene

b)

2-ethyl-4-methylpent-3-ene

c)

2-methyl-4-ethylpent-3-ene

d)

2,4-dimethylhex-2-ene

11.

Which statements about the chlorine free radical are correct?


I. It has 18 electrons.

II. It is an uncharged species.

III. It is formed by homolytic fission.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

12.

Which statement is correct about the polymerization of ethene to poly(ethene)?

a)

The polymer is an alkene.

b)

The monomer ethene and the repeating unit have the same empirical formula.

c)

The monomer ethene is less reactive than the polymer.

d)

The polymer contains C−C single and C=C double bonds.

13.

Applying IUPAC rules, what is the name of CH3CH(CH3)CH2COOH?

a)

2,3-dimethylpropanoic acid

b)

Pentanoic acid

c)

3-methylbutanoic acid

d)

2-methylbutanoic acid

14.

Which of the following functional groups are present in aspirin?

a)

Hydroxyl (alcohol) and ester

b)

Carboxyl (carboxylic acid) and ester

c)

Carboxyl (carboxylic acid) and carbonyl (ketone)

d)

Hydroxyl (alcohol) and carbonyl (ketone)

15.

Which statements are correct for the reaction of ethene with bromine in the absence of ultraviolet light?


I. It is an addition reaction.

II. The organic product is colourless.

III. The organic product is saturated.

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III

16.

Which combination best describes the substitution reaction between bromoethane and dilute aqueous sodium hydroxide?


CH3CH2Br + OH → CH3CH2OH + Br

a)

A

b)

B

c)

C

d)

D

17.

Which pair of compounds can be distinguished by reacting them with dilute bromine water in the dark?

a)

CH3CH2COOH and CH3CH2CHO

b)

CH3CH2CHCHCH3 and CH3CH2CH2CH2CH3

c)

CH3CH2CH(CH3)2 and CH3CH2CH2CH2CH3

d)

CH3CH2CH2CHBrCH3 and CH3CH2CHBrCH2CH3

18.

Which is not a possible product when propane, C3H8, reacts with chlorine in sunlight?

a)

H2

b)

C6H14

c)

C3H7Cl

d)

Cl2

19.

Which compound is most soluble in water?

a)

CH3CH2CHO

b)

CH3CH2CH2CHO

c)

CH3CH2CO2H

d)

CH3CH2CH2CO2H

20.

Which are features of successive members of a homologous series?

I. Similar chemical properties

II. Same general formula

III. Differ by −CH2

a)

I and II only

b)

I and III only

c)

II and III only

d)

I, II and III