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CARBONYL COMPOUNDS

Total questions: 10

Worksheet time: 7mins

Name
Class
Date
1.

Which of the following is not a carbonyl compound?

a)
b)
c)
d)
2.

An organic compound X has the following chemical properties.

· Forms a yellow precipitate when tested with 2,4-dinitrophenylhydrazine.

· Forms a yellow precipitate when it reacts with an excess iodine in alkaline solution.

Which of the following compounds is X?

a)
b)
c)
d)
3.

Which of the following alcohols can be oxidised to 2-methyl-3-pentanone?

a)

CH3CH2CH(OH)CH3

b)

CH3CH(OH)CH2CH2CH3

c)

(CH3)3CCH(OH)CH3

d)

(CH3)2CHCH(OH)CH2CH3

4.

The following reaction scheme shows how propene can be prepared from propanal in two stages using reagents X and Y. Which of the following are the reagents X and Y?


X Y

CH3CH2CHO → CH3CH2CH2OH → H3CH=CH2

a)

X: LiAlH4 ; Y: KOH, ethanol, reflux

b)

X: NaBH4 ; Y: conc.H2SO4, heat

c)

X: dillute H2SO4 ; Y: conc.ethanol, reflux

d)

X: dillute H2SO4 ; Y: KOH, ethanol, reflux

5.

On heating compound X with acidified KMnO4, compound Y is obtained. Compound Y does not react with Fehling’s solution. X and Y are most likely to be,


Compound X Compound Y

a)

CH3COCH3 CH3COOH

b)

CH3CH(OH)CH3 CH3COCH3

c)

CH3CH2CH2OH CH3COCH3

d)

CH3CH2CH2OH CH3CH2CHO

6.

Which substance would test positively with 2,4-DNPH but negatively with Tollens’ reagent?

a)

Propanal

b)

Propanone

c)

Propanoic acid

d)

1-propanol

7.

Acetone reacts with HCN to form a cyanohydrin. It is an example of

a)

Electrophilic addition

b)

Electrophilic substituition

c)

Nucleophilic addition

d)

Nucleophilic substituition

8.

Which reagent would you choose to convert 1-pentanol to pentanal?

a)

PCC in CH2Cl2

b)

K2Cr2O7 with aqueous H2SO4

c)

KMnO4 with aqueous H2SO4

d)

KOH, ethanol, reflux

9.

Which statement about butanone is correct?

a)

The C=O of butanone is polar with O δ

b)

Butanone can be prepared by reduction of 1-butanol

c)

Butanone forms brick red precipitate with Fehling’s reagent

d)

Butanone form cloudy solution with Lucas test

10.

What is the reagent to differentiate between a benzaldehyde and a ketone

a)

Acidified potassium dichromate (VI) solution

b)

Tollen’s reagent, [Ag(NH3)2]+

c)

Fehling’s solution containing complex ions of Cu2+